Hydrocarbon halides

Hydrocarbon halide, or hydrocarbon for short, refers to the product produced during the process of hydrogen atoms replaced by by halogen (fluorine, chlorine, bromine, iodine) in the hydrocarbon molecules. According to the different hydrocarbon groups, it could be divided into categories like aliphatic halogenated hydrocarbons (including saturated and unsaturated halogenated hydrocarbons), aromatic halogenated hydrocarbons. According to the amount of halogen atoms contained in the molecule, it could be divided into categories like halogenated hydrocarbons, dihalogenated hydrocarbons and polyhalogenated hydrocarbons. Most of the halogenated hydrocarbons are liquid. The proportion of Iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. They are insoluble in water and could be dissolved in any proportion with hydrocarbons, they also could dissolve many other organics. The proportion of Hydrocarbon halide would decreases with the increase of the amount of carbon atoms. When there are the same hydrocarbon groups, the boiling point and the proportion of the halogenated hydrocarbons would increase in the order of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons. In the isomer, the more branches it gets, the lower boiling point it has. Most of these substances are toxic and can burn. And their combustion properties decrease with the increase of the amount of halogen atoms in the compound. When it comes to storage, fire hazard should be managed in A, B, C three categories according to fire risk indicators. When it catch fire, the gas should be treated by the C class of fire treatment, liquid by B class of fire treatment. Eenough attention should be payed to anti-virus.
The amount of naturally occurring halo hydrocarbons is very small, and the majority of halo hydrocarbons are synthesized by halogenation of alkanes, and compounded by unsaturated hydrocarbons. It also could be compounded during the reaction between alcohol with hydrohalic acid.
The amount of Halohydrocarbons are more isomers than corresponding hydrocarbons. Apart from the carbon isomerism, unsaturated bond position isomerization, cis-trans isomerism and optical isomerism, there are halogen atom isomerizations as well.. when the Halogenated hydrocarbon was named, the hydrocarbon plays a rule as the matrix while halogen atom plays as substituents. The position, number and name of halogen should be lined out before the name of the hydrocarbon. At room temperature, apart from methyl chloride, methyl bromide, ethyl chloride, vinyl chloride and others which are gas in room temperature, the halo hydrocarbon is liquid in general and the highly  halogenated hydrocarbon is solid.
Halohydrocarbons is not dissolvable in water, but soluble in a variety of organic solvents, and can be dissolved in a variety of weak polarity and non-polar organic compounds. So it  is a kind of commonly used solvent. The relative density of iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. The boiling point of halogenated hydrocarbons increases with the increasing atomic amount of halogen atoms. The boiling point of the same series of halogenated hydrocarbons increases with increase of the amount of carbon chain. The more branched the isomer, the lower the boiling point would it have (except from fluorinated alkanes).
The chemical property of halogenated hydrocarbons is much more active than paraffin, so  halogenated hydrocarbons can produce a variety of chemical reactions, and turn them into various types of compounds. It has an important position in organic synthesis. Halo hydrocarbon has been applied widely in many trades, apart from being used as a solvent, it also could be used as refrigerant, extinguishing agent, anesthetics and preservatives.
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Structure Chemical Name CAS MF
4,4'-Dibromobiphenyl 4,4'-Dibromobiphenyl 92-86-4 C12H8Br2
1-BROMO-2,4-DICHLOROBENZENE 1-BROMO-2,4-DICHLOROBENZENE 1193-72-2 C6H3BrCl2
1,3-Dibromobenzene 1,3-Dibromobenzene 108-36-1 C6H4Br2
1,2-Dibromo-4,5-difluorobenzene 1,2-Dibromo-4,5-difluorobenzene 64695-78-9 C6H2Br2F2
2-Bromonaphthalene 2-Bromonaphthalene 580-13-2 C10H7Br
1-Bromo-3-methylbutane 1-Bromo-3-methylbutane 107-82-4 C5H11Br
1,3-Difluorobenzene 1,3-Difluorobenzene 372-18-9 C6H4F2
2-Chlorotrityl chloride 2-Chlorotrityl chloride 42074-68-0 C19H14Cl2
2-Chloropropane 2-Chloropropane 75-29-6 C3H7Cl
2-Bromobutane 2-Bromobutane 78-76-2 C4H9Br
4-Chlorotoluene 4-Chlorotoluene 106-43-4 C7H7Cl
Allyl chloride Allyl chloride 107-05-1 C3H5Cl
1,3-DIIODOBENZENE 1,3-DIIODOBENZENE 626-00-6 C6H4I2
1,3-Bis(bromomethyl)benzene 1,3-Bis(bromomethyl)benzene 626-15-3 C8H8Br2
1,3-Dibromo-5-fluorobenzene 1,3-Dibromo-5-fluorobenzene 1435-51-4 C6H3Br2F
1,3,5-Trifluorobenzene 1,3,5-Trifluorobenzene 372-38-3 C6H3F3
1-Bromo-2,4,5-trifluorobenzene 1-Bromo-2,4,5-trifluorobenzene 327-52-6 C6H2BrF3
1,2-Diiodobenzene 1,2-Diiodobenzene 615-42-9 C6H4I2
1,2-Dichloro-4-(chloromethyl)benzene 1,2-Dichloro-4-(chloromethyl)benzene 102-47-6 C7H5Cl3
4-Bromophenylacetylene 4-Bromophenylacetylene 766-96-1 C8H5Br
p-Fluorotoluene p-Fluorotoluene 352-32-9 C7H7F
2-Methylbenzyl bromide 2-Methylbenzyl bromide 89-92-9 C8H9Br
1-Bromo-3,5-dichlorobenzene 1-Bromo-3,5-dichlorobenzene 19752-55-7 C6H3BrCl2
2-Chlorobenzyl bromide 2-Chlorobenzyl bromide 611-17-6 C7H6BrCl
Dichloromethane Dichloromethane 75-09-2 CH2Cl2
1-BROMO-2,3,4,5-TETRAFLUOROBENZENE 1-BROMO-2,3,4,5-TETRAFLUOROBENZENE 1074-91-5 C6HBrF4
Dibromomethane Dibromomethane 74-95-3 CH2Br2
1-Fluoro-2-iodobenzene 1-Fluoro-2-iodobenzene 348-52-7 C6H4FI
4-Bromo-2-fluorobiphenyl 4-Bromo-2-fluorobiphenyl 41604-19-7 C12H8BrF
1-Chloro-4-fluorobenzene 1-Chloro-4-fluorobenzene 352-33-0 C6H4ClF
1-Fluoronaphthalene 1-Fluoronaphthalene 321-38-0 C10H7F
3-FLUORO-O-XYLENE 3-FLUORO-O-XYLENE 443-82-3 C8H9F
1-Bromo-2,3-difluorobenzene 1-Bromo-2,3-difluorobenzene 38573-88-5 C6H3BrF2
4-Bromo-2-chloro-1-fluorobenzene 4-Bromo-2-chloro-1-fluorobenzene 60811-21-4 C6H3BrClF
1,2-Difluorobenzene 1,2-Difluorobenzene 367-11-3 C6H4F2
9-Bromophenanthrene 9-Bromophenanthrene 573-17-1 C14H9Br
1-Bromopropane 1-Bromopropane 106-94-5 C3H7Br
Bromoethane Bromoethane 74-96-4 C2H5Br
3,5-Bis(trifluoromethyl)benzyl chloride 3,5-Bis(trifluoromethyl)benzyl chloride 75462-59-8 C9H5ClF6
3-Bromotoluene 3-Bromotoluene 591-17-3 C7H7Br
1-Bromo-3-phenylpropane 1-Bromo-3-phenylpropane 637-59-2 C9H11Br
1-Bromo-4-chloro-2-methylbenzene 1-Bromo-4-chloro-2-methylbenzene 14495-51-3 C7H6BrCl
1-Bromo-3-chloropropane 1-Bromo-3-chloropropane 109-70-6 C3H6BrCl
3-BROMOCHLOROBENZENE 3-BROMOCHLOROBENZENE 108-37-2 C6H4BrCl
Iodoethane Iodoethane 75-03-6 C2H5I
4-Chlorobenzyl chloride 4-Chlorobenzyl chloride 104-83-6 C7H6Cl2
(1-Bromoethyl)benzene (1-Bromoethyl)benzene 585-71-7 C8H9Br
2,6-Dichlorobenzyl chloride 2,6-Dichlorobenzyl chloride 2014-83-7 C7H5Cl3
PENTAFLUOROBENZYL BROMIDE PENTAFLUOROBENZYL BROMIDE 1765-40-8 C7H2BrF5
2-Chlorotoluene 2-Chlorotoluene 95-49-8 C7H7Cl
Chlorodiphenylmethane Chlorodiphenylmethane 90-99-3 C13H11Cl
3-Chloro-2-methylpropene 3-Chloro-2-methylpropene 563-47-3 C4H7Cl
1,2-Dichlorobenzene 1,2-Dichlorobenzene 95-50-1 C6H4Cl2
1,3-Dichloro-2-fluorobenzene 1,3-Dichloro-2-fluorobenzene 2268-05-5 C6H3Cl2F
2-Bromoethylbenzene 2-Bromoethylbenzene 1973-22-4 C8H9Br
alpha-Chloro-o-fluorotoluene alpha-Chloro-o-fluorotoluene 345-35-7 C7H6ClF
1-Bromopyrene 1-Bromopyrene 1714-29-0 C16H9Br
(E)-1,4-Dibromobut-2-ene (E)-1,4-Dibromobut-2-ene 821-06-7 C4H6Br2
3-Methylbenzyl chloride 3-Methylbenzyl chloride 620-19-9 C8H9Cl
4-Iodobenzyl bromide 4-Iodobenzyl bromide 16004-15-2 C7H6BrI
3-CHLORO-4-FLUOROIODOBENZENE 3-CHLORO-4-FLUOROIODOBENZENE 156150-67-3 C6H3ClFI
4-tert-Butylbenzyl chloride 4-tert-Butylbenzyl chloride 19692-45-6 C11H15Cl
Bromopentafluorobenzene Bromopentafluorobenzene 344-04-7 C6BrF5
3-Chlorotoluene 3-Chlorotoluene 108-41-8 C7H7Cl
1,3-Dibromo-5-chlorobenzene 1,3-Dibromo-5-chlorobenzene 14862-52-3 C6H3Br2Cl
4-Chlorophenylacetylene 4-Chlorophenylacetylene 873-73-4 C8H5Cl
4-Chlorobenzhydrylchloride 4-Chlorobenzhydrylchloride 134-83-8 C13H10Cl2
1-Bromo-4-butylbenzene 1-Bromo-4-butylbenzene 41492-05-1 C10H13Br
1,3,5-Tris(trifluoromethyl)benzene 1,3,5-Tris(trifluoromethyl)benzene 729-81-7 C9H3F9
1,2,3,4-Tetrafluorobenzene 1,2,3,4-Tetrafluorobenzene 551-62-2 C6H2F4
1,4-Dichlorobutane 1,4-Dichlorobutane 110-56-5 C4H8Cl2
Fluorobenzene Fluorobenzene 462-06-6 C6H5F
1,4-Difluorobenzene 1,4-Difluorobenzene 540-36-3 C6H4F2
Acryloyl chloride Acryloyl chloride 814-68-6 C3H3ClO
1-Bromooctane 1-Bromooctane 111-83-1 C8H17Br
2-Iodo-1,3-dimethylbenzene 2-Iodo-1,3-dimethylbenzene 608-28-6 C8H9I
1,7-DIBROMOHEPTANE 1,7-DIBROMOHEPTANE 4549-31-9 C7H14Br2
2,4-Dimethylbromobenzene 2,4-Dimethylbromobenzene 583-70-0 C8H9Br
1,3-Dichloro-4-fluorobenzene 1,3-Dichloro-4-fluorobenzene 1435-48-9 C6H3Cl2F
4-Fluorophenylacetylene 4-Fluorophenylacetylene 766-98-3 C8H5F
1-Chlorobutane 1-Chlorobutane 109-69-3 C4H9Cl
9-Bromoanthracene 9-Bromoanthracene 1564-64-3 C14H9Br
3,5-Dibromotoluene 3,5-Dibromotoluene 1611-92-3 C7H6Br2
3,4-Dichlorobenzyl bromide 3,4-Dichlorobenzyl bromide 18880-04-1 C7H5BrCl2
Tribromobenzene Tribromobenzene 626-39-1 C6H3Br3
1-Bromo-4-propylbenzene 1-Bromo-4-propylbenzene 588-93-2 C9H11Br
Bromobenzene Bromobenzene 108-86-1 C6H5Br
4-Chloro-1,2-dimethylbenzene 4-Chloro-1,2-dimethylbenzene 615-60-1 C8H9Cl
4-Chlorobenzyl bromide 4-Chlorobenzyl bromide 622-95-7 C7H6BrCl
9,10-Dibromoanthracene 9,10-Dibromoanthracene 523-27-3 C14H8Br2
4-Bromotoluene 4-Bromotoluene 106-38-7 C7H7Br
2,6-Dichlorobenzyl bromide 2,6-Dichlorobenzyl bromide 20443-98-5 C7H5BrCl2
1,2-Dibromoethane 1,2-Dibromoethane 106-93-4 C2H4Br2
1-Bromo-3,4-dichlorobenzene 1-Bromo-3,4-dichlorobenzene 18282-59-2 C6H3BrCl2
Chlorobenzene Chlorobenzene 108-90-7 C6H5Cl
2,5-DIFLUOROIODOBENZENE 2,5-DIFLUOROIODOBENZENE 2265-92-1 C6H3F2I
alpha,alpha'-Dichloro-p-xylene alpha,alpha'-Dichloro-p-xylene 623-25-6 C8H8Cl2
1,2,3-Trifluorobenzene 1,2,3-Trifluorobenzene 1489-53-8 C6H3F3
Bromochloromethane Bromochloromethane 74-97-5 CH2BrCl
2-(Bromomethyl)naphthalene 2-(Bromomethyl)naphthalene 939-26-4 C11H9Br
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