1-Fluoro-2-iodobenzene

1-Fluoro-2-iodobenzene Basic information

Product Name:	1-Fluoro-2-iodobenzene
Synonyms:	1-fluoro-2-iodo-benzen;O-FLUOROIODOBENZENE;O-IODO FLUOROBENZENE;uoroiodobenzene;2-Fluoroiodobenzene 99%, contains copper as stabilizer;1-Fluoro-2-iodobenzene, Stabilized with copper;CL055;2-FLUOROIODOBENZENE
CAS:	348-52-7
MF:	C6H4FI
MW:	222
EINECS:	206-477-3
Product Categories:	Aryl Fluorinated Building Blocks;Building Blocks;Chemical Synthesis;Fluorinated Building Blocks;Halogenated Hydrocarbons;Organic Building Blocks;Aromatic Esters;Fluorobenzene;Miscellaneous;Fluorine Compounds;Iodine Compounds;Aryl;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;C6;Halogenated Hydrocarbons
Mol File:	348-52-7.mol

1-Fluoro-2-iodobenzene Chemical Properties

Melting point	−41-−40 °C(lit.)
Boiling point	188-189 °C(lit.)
density	1.903 g/mL at 25 °C(lit.)
refractive index	n20/D 1.59(lit.)
Fp	160 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
form	Liquid
Specific Gravity	1.903
color	Clear light yellow
Sensitive	Light Sensitive
BRN	2039770
CAS DataBase Reference	348-52-7(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-fluoro-2-iodo-(348-52-7)
EPA Substance Registry System	o-Fluoroiodobenzene (348-52-7)

Safety Information

Hazard Codes	Xn,N,Xi
Risk Statements	22-37/38-41-51/53-36/37/38
Safety Statements	26-39-61-37/39
RIDADR	UN3082 - class 9 - PG 3 - DOT NA1993 - Environmentally hazardous substances, liquid, n.o.s. HI: all (not BR)
WGK Germany	2
TSCA	T
HazardClass	IRRITANT
HS Code	29039990

MSDS Information

Provider	Language
2-Fluoroiodobenzene	English
SigmaAldrich	English
ACROS	English
ALFA	English

1-Fluoro-2-iodobenzene Usage And Synthesis

Chemical Properties	Clear colourless to light yellow liquid
Uses	suzuki reaction
Uses	2-Fluoroiodobenzene was used in the synthesis of: bridged biphenyl compounds, 1-fluoro-8-methylbiphenylene and 4-fluoro-5-methylfluorene 2-acetyl-7-iodo-1-benzothiophene chiral o-phosphanophenyl sulfoxides
Synthesis Reference(s)	Synthetic Communications, 20, p. 1701, 1990 DOI: 10.1080/00397919008053092

1-Fluoro-2-iodobenzene Preparation Products And Raw materials

Raw materials	(2-fluoro-4-trimethylsilylphenyl)-trimethylsilane-->Sodium trifluoromethanesulfinate-->(2-Fluorophenyl)trimethylsilane-->1-FLUORO-2-[(TRIFLUOROMETHYL)SULFONYL]BENZENE-->2-Bromofluorobenzene-->2-Fluorobenzoyl chloride
Preparation Products	2-FLUOROPHENYLBORONIC ACID-->2-Fluorophenylboronic acid-->5-Fluoro-1-tetralone-->2-Fluorostyrene-->o-fluorocinnamic acid-->2-Propynoic acid, 3-(2-fluorophenyl)-, methyl ester

1,4-Diiodobenzene Iodobenzene [BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE Fluorine (Diacetoxyiodo)benzene 4-Fluoro-3-iodobenzoic acid ethyl ester 2-CHLORO-1,3-DIFLUORO-4-IODOBENZENE alpha-Chloro-o-fluorotoluene 2-(Trifluoromethyl)benzoic acid 4-CHLORO-2-FLUORO-1-IODOBENZENE,1-CHLORO-3-FLUORO-4-IODOBENZENE 1,4-DIIODOTETRAFLUOROBENZENE 2,4-Difluoroiodobenzene 1-Fluoro-2-iodobenzene 1-Fluoro-2-nitrobenzene 3,5-DIBROMO-1-FLUORO-2-IODOBENZENE 1,2-Diiodobenzene 2-Methylbenzotrifluoride 1-Bromo-5-chloro-3-fluoro-2-iodobenzene

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