ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon halides 3-BROMOCHLOROBENZENE

3-BROMOCHLOROBENZENE

3-BROMOCHLOROBENZENE Basic information
Product Name:3-BROMOCHLOROBENZENE
Synonyms:1-bromo-3-chloro-benzen;1-Chloro-3-bromobenzene;3-Bromo-1-chlorobenzene;1-BROMO-3-CHLOROBENZENE;3-BROMOCHLOROBENZENE;M-CHLOROBROMOBENZENE;M-BROMOCHLOROBENZENE;3-BROMOCHLOROBENZENE 99%
CAS:108-37-2
MF:C6H4BrCl
MW:191.45
EINECS:203-575-8
Product Categories:alkyl bromide| alkyl chloride;Building Blocks;Bromine Compounds;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Aromatic Halides (substituted);Chlorine Compounds;Aryl;C6;Halogenated Hydrocarbons
Mol File:108-37-2.mol
3-BROMOCHLOROBENZENE Structure
3-BROMOCHLOROBENZENE Chemical Properties
Melting point -21.5 °C
Boiling point 196 °C(lit.)
density 1.63 g/mL at 25 °C(lit.)
refractive index n20/D 1.576(lit.)
Fp 177 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
color Clear colorless to light yellow
Specific Gravity1.630
Water Solubility Insoluble
BRN 1446353
CAS DataBase Reference108-37-2(CAS DataBase Reference)
NIST Chemistry Reference3-Chlorobromobenzene(108-37-2)
EPA Substance Registry SystemBenzene, 1-bromo-3-chloro- (108-37-2)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/22
Safety Statements 26-36-37/39
WGK Germany 3
RTECS CY9005000
Hazard Note Irritant
TSCA Yes
HS Code 29039990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
3-BROMOCHLOROBENZENE Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS TO LIGHT YELLOW LIQUID
Uses1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
Synthesis Reference(s)The Journal of Organic Chemistry, 52, p. 664, 1987 DOI: 10.1021/jo00380a031
General Description1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
3-BROMOCHLOROBENZENE Preparation Products And Raw materials
Preparation Products1-(3-Chlorophenyl)-1-ethanol-->1-(3-Chlorphenyl)piperazine-->INDANOFAN-->2,7-Dichlorofluorene-->1-Chloro-3-ethylbenzene-->3-CHLOROPHENYLBORONIC ACID, PINACOL ESTER-->3-CHLORO-N-METHYLANILINE-->Methyl 3-chlorobenzoate-->2,3'-Dichloroacetophenone-->3-CHLOROPHENYL CYCLOPROPYL KETONE-->3-Cyclopropyl-benzeneboronic acid -->1-BROMO-3-CHLORO-5-IODOBENZENE-->Dimethyl isophthalate
4-BROMO-2-CHLOROACETANILIDE Bromochlorophenol Blue sodium salt 2-Bromo-4-chloroaniline 2-BROMO-6-CHLORO-4-NITROANILINE 1-Bromo-2,3-dichlorobenzene 2'-BROMO-4'-CHLOROACETANILIDE 4-Bromo-2-chlorobenzonitrile 2-BROMO-4,6-DICHLOROANILINE N-(4-BROMO-2-CHLOROPHENYL)MALEAMIC ACID 2-Bromo-4-chlorophenol 1-Bromo-3,4-dichlorobenzene 2-BROMO-4-CHLORO-6-NITROPHENOL 3-BROMO-5-CHLORO-4-IODOBENZOTRIFLUORIDE 4-BROMO-2-CHLOROPHENYL ISOTHIOCYANATE 2,6-DIBROMO-4-CHLOROPHENOL 2,4-DIBROMO-3,6-DICHLOROANILINE 3-BROMOCHLOROBENZENE 2-CHLORO-4,6-DIBROMOANILINE
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