2-(Bromomethyl)naphthalene

2-(Bromomethyl)naphthalene Basic information
Product Name:2-(Bromomethyl)naphthalene
Synonyms:2-(BROMOMETHYL)NAPHTHALENE;2-BMN;BROMOMETHYLNAPTHALENE-2;2-Bromomethylnaphthalene98%;2-(Bromomethyl)naphthalene,96%;(2-Naphtylmethyl) bromide;Naphthalene, 2-(bromomethyl)-;2-naphthylmethyl bromide
CAS:939-26-4
MF:C11H9Br
MW:221.09
EINECS:213-359-5
Product Categories:Naphthalene series;Aryl;C9 to C12;Halogenated Hydrocarbons;Naphthalene derivatives
Mol File:939-26-4.mol
2-(Bromomethyl)naphthalene Structure
2-(Bromomethyl)naphthalene Chemical Properties
Melting point 51-54 °C(lit.)
Boiling point 213 °C100 mm Hg(lit.)
density 1.3971 (rough estimate)
refractive index 1.6411 (estimate)
Fp >230 °F
storage temp. 2-8°C
solubility Chloroform (Sparingly), Ethyl Acetate (Very Slightly)
form Fine Crystalline Powder
color Slightly yellow to light beige
Water Solubility Soluble in water (reacts), and chloroform.
BRN 636546
CAS DataBase Reference939-26-4(CAS DataBase Reference)
NIST Chemistry ReferenceNaphthalene, 2-(bromomethyl)-(939-26-4)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-43-36/37/38-36
Safety Statements 26-28-36/37/39-45-37-27
RIDADR UN 3261 8/PG 2
WGK Germany 3
10-21
Hazard Note Corrosive/Keep Cold
HazardClass 8
PackingGroup II
HS Code 29033036
MSDS Information
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2-(Bromomethyl)naphthalene Usage And Synthesis
Chemical PropertiesWhite to cream solid
Uses2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene , 2-naphthylmethyl azide , 2-naphthalenecarboxaldehyde , diselenide, bis(2-naphthalenylmethyl) , 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis[1-(2-naphthalenylmethyl).
UsesIt is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.
Purification MethodsDissolve the bromo compound in toluene, wash it with saturated aqueous NaHCO3, dry (Mg SO4), evaporate, fractionally distil the residue and recrystallise the solidified distillate from EtOH. [Chapman & Williams J Chem Soc 5044, 1952, Bergmann & Szmuszkovicz Bull Soc Chim Fr 20 566 1953, Beilstein 5 IV 1698.]
2-BROMOMETHYLFLUORANTHENE 2-(BROMOMETHYL)NAPHTHALENE 1G SALOR-INT L170046-1EA 2,7-BIS(BROMOMETHYL)NAPHTHALENE 2-NAPHTHOYL BROMIDE BENZOYL HYDRAZINE 1-BROMOMETHYLFLUORANTHENE 2-BROMO-6-(BROMOMETHYL)NAPHTHALENE 1-BROMOMETHYL NAPHTHALENE 99.73%,1-BROMOMETHYL NAPHTHALENE 1-BROMO-6,8-DIFLUORO-3,4-DIHYDRO-PHENANTHRENE 9,10-Dichloro-2,6-bis(bromomethyl)anthracene 3-(BROMOMETHYL)PYRENE 2,6-DIMETHYLNAPHTHALENE 1,8-BIS(BROMOMETHYL)NAPHTHALENE 1-BROMO-2-(BROMOMETHYL)-6-FLUORONAPHTHALENE 1-BROMO-3,4-DIHYDRO-PHENANTHRENE 6-bromomethylbenzo(a)pyrene 2,6-BIS(BROMOMETHYL)NAPHTHALENE 1-BROMO-6-FLUORO-3,4-DIHYDRO-PHENANTHRENE

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