1,2-Dichloro-4-(chloromethyl)benzene

1,2-Dichloro-4-(chloromethyl)benzene Basic information
Product Name:1,2-Dichloro-4-(chloromethyl)benzene
Synonyms:1,2-dichloro-4-(chloromethyl)-benzen;Benzene, 3,4-dichloro-1-chloromethyl;Benzene,1,2-dichloro-4-(chloromethyl)-;Toluene, alpha,3,4-trichloro-;DICHLOROBENZYL-3,4 CHLORIDE;1,2-DICHLORO-4-(CHLOROMETHYL)BENZENE;3,4,ALPHA-TRICHLOROTOLUENE;3,4,α-Trichlorotoluene
CAS:102-47-6
MF:C7H5Cl3
MW:195.47
EINECS:203-033-0
Product Categories:K00001
Mol File:102-47-6.mol
1,2-Dichloro-4-(chloromethyl)benzene Structure
1,2-Dichloro-4-(chloromethyl)benzene Chemical Properties
Melting point -3 °C
Boiling point 122-124 °C14 mm Hg(lit.)
density 1.411 g/mL at 25 °C(lit.)
refractive index n20/D 1.577(lit.)
Fp 155 °C
storage temp. Store below +30°C.
solubility Chloroform, Methanol (Slightly)
form Liquid
Specific Gravity1.409
color Clear colorless to very slightly yellow
BRN 386644
CAS DataBase Reference102-47-6(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1,2-dichloro-4-(chloromethyl)-(102-47-6)
EPA Substance Registry SystemBenzene, 1,2-dichloro-4-(chloromethyl)- (102-47-6)
Safety Information
Hazard Codes C
Risk Statements 34-36/37
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
19
Hazard Note Corrosive
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29036990
MSDS Information
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1,2-Dichloro-4-(chloromethyl)benzene Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS TO VERY SLIGHTLY YELLOW LIQUID
Uses3,4-Dichlorobenzyl chloride has been used:
  • in Friedel-Crafts synthesis of 4-(3,4-dichlorophenyl)-3,4-dihydro-1(2H)-naphthalenone, a key intermediate for the synthesis of sertraline
  • as alkylating agent in synthesis of poly(ether ketone)s having pendant sulfonic acid groups
  • in preparation of 5,6-dichloro-2-(3,4-dichlorobenzylthio)benzimidazole
1,2-Dichloro-4-(chloromethyl)benzene Preparation Products And Raw materials
Preparation Products1-(3,4-DICHLOROBENZYL)PIPERAZINE-->4-[(3,4-DICHLOROBENZYL)OXY]BENZALDEHYDE-->3,4-Dichlorobenzaldehyde-->3-[(3,4-DICHLOROBENZYL)OXY]PYRIDIN-2-AMINE-->1H-Imidazole, 2-[[(3,4-dichlorophenyl)methyl]thio]-4,5-dihydro--->5-AMino-1-(3,4-dichlorobenzyl)-1H-indazol-3-ol-->O-(3,4-dichlorobenzyl)hydroxylaMine-->3,4-DICHLOROBENZYL MERCAPTAN
1,3-DICHLORO-5-(CHLOROMETHYL)BENZENE,1,3-Dichloro-5-(chloromethyl)benzene, 95+% 2-CHLORO-2-(3,4-DICHLORO-PHENYL)-ETHANOL Benzyl chloride trichloro(chloromethyl)benzene PENTACHLOROBENZOYL CHLORIDE ALPHA-2,3,4,5,6-HEXACHLOROSTYRENE 2,3,4,5-Tetrachlorobenzoyl chloride ALPHA,ALPHA',2,4,5,6-HEXACHLORO-M-XYLENE 2,3,4-TRICHLORO-5-FLUOROBENZOIC CHLORIDE OCTACHLOROSTYRENE 3,4-Dichlorobenzotrichloride 1,2-Dichloro-4-(chloromethyl)benzene 1,2-dichloro-3-(chloromethyl)benzene 1,4-Dichloro-2-(chloromethyl)benzen 3,4-Dichlorotoluene 1,3-DICHLORO-2-(CHLOROMETHYL)BENZENE 2,3-Dichlorobenzoyl chloride 2,4-dichloro-1-chloromethyl-benzen

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