Fluorobenzene

Fluorobenzene Chemical Properties
Melting point -42 °C
Boiling point 85 °C(lit.)
density 1.024 g/mL at 25 °C(lit.)
vapor density 3.31 (vs air)
vapor pressure 81hPa at 20℃
refractive index n20/D 1.465(lit.)
Fp 9 °F
storage temp. 2-8°C
solubility 1.54g/l
form Liquid
Specific Gravity1.024
color Clear colorless
Relative polarity3.3
explosive limit1.3-8.9%(V)
Water Solubility INSOLUBLE
Merck 14,4170
BRN 1236623
Stability:Stable. Incompatible with oxidizing agents. Highly flammable - note low flash point.
InChIKeyPYLWMHQQBFSUBP-UHFFFAOYSA-N
LogP2.27 at 25℃
CAS DataBase Reference462-06-6(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, fluoro-(462-06-6)
EPA Substance Registry SystemFluorobenzene (462-06-6)
Safety Information
Hazard Codes F,Xi,T
Risk Statements 36/37/38-11-39/23/24/25-23/24/25-52/53-36
Safety Statements 16-26-36-7-33-29-45-36/37-61-7/9
RIDADR UN 2387 3/PG 2
WGK Germany 2
RTECS DA0800000
Hazard Note Flammable
TSCA T
HazardClass 3
PackingGroup II
HS Code 29039990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Fluorobenzene Usage And Synthesis
DescriptionFluorobenzene is a colourless, highly flammable liquid, stable and incompatible with oxidising agents. It is not compatible with oxidising agents such as perchlorates, peroxides, permanganates, chlorates, nitrates, chlorine, bromine and fluorine, ammonium nitrate, chromic acid, halogens, and nitric acid. It is used as an insecticide and as a reagent for plastic and resin polymers.
Chemical Propertiescolourless liquid
Chemical PropertiesFluorobenzene is a colorless liquid.
UsesFluorobenzene is used as a reagent for plastic or resin polymers. It acts as a solvent for highly reactive species. On fluorination of fluorobenzene it gives 1,2-difluorobenzene. It is also used as a material in making medicine.
UsesInsecticide and larvicide intermediate, identification reagent for plastic or resin polymers.
DefinitionChEBI: The simplest member of the class of monofluorobenzenes that is benzene carrying a single fluoro substituent.
Synthesis Reference(s)Journal of the American Chemical Society, 106, p. 452, 1984 DOI: 10.1021/ja00314a050
The Journal of Organic Chemistry, 30, p. 3170, 1965 DOI: 10.1021/jo01020a073
General DescriptionA clear, colorless liquid with a characteristic aromatic odor. About the same density as water. Flash point 5°F. Vapors heavier than air. May irritate the skin, eyes, and mucous membranes. Used as an insecticide, larvacide and as a reagent for plastic or resin polymers.
Air & Water ReactionsHighly flammable. Slightly soluble in water.
Reactivity ProfileIncompatible with strong oxidizing agents.
HazardFlammable, dangerous fire risk. Irritant.
Health HazardIrritating to skin, eyes and mucous membranes. Repeated exposure of skin may cause dermatitis due to defatting action. Chronic inhalation of vapors or mist may result to damage to lungs, liver and kidneys. Acute vapor exposures can cause symptoms ranging from coughing to transient anesthesia and central nervous system depression.
Flammability and ExplosibilityHighlyflammable
Safety Profile: Mddly toxic by ingestion and inhalation. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. To fight fire, use water spray, mist, foam, dry chemical, CO2. When heated to decomposition it emits toxic fumes of F-
Potential ExposureFluorobenzene is used as an insecti cide and as a reagent for plastic or resin polymers.
ShippingUN2387 Fluorobenzene, Hazard Class: 3; Labels: 3-Flammable liquid.
Purification MethodsDry fluorobenzene for several days with P2O5, then fractionally distil it. [Beilstein 5 H 198, 5 IV 632.]
IncompatibilitiesVapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, perox ides, permanganates, perchlorates, chlorine, bromine, fluo rine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
Hydrogen fluoride Ammonium hydrogen difluoride FENFLURAMINE 3,4-Difluorobenzonitrile Transfluthrin Boron trifluoride Fluorobenzene trifluorobenzene 4-Fluorobenzonitrile 4-Fluorobenzaldehyde Aluminum fluoride Sulfur hexafluoride 1,2-Difluorobenzene Sodium fluoride Florfenicol 2,4-DINITRO-1-FLUOROBENZENE 4-Fluorophenol 1,3-Difluorobenzene

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