ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon halides 2-Methylbenzyl bromide

2-Methylbenzyl bromide

2-Methylbenzyl bromide Basic information
Product Name:2-Methylbenzyl bromide
Synonyms:1-(bromomethyl)-2-methyl-benzen;2-Xylyl bromide;2-xylylbromide;alpha-Bromo-ortho-xylene;alpha-bromo-o-xylen;o-Xylene, alpha-bromo-;O-(BROMOMETHYL)TOLUENE;O-XYLENE BIS(TRIPHENYLPHOSPONIUM BROMIDE)
CAS:89-92-9
MF:C8H9Br
MW:185.06
EINECS:201-951-6
Product Categories:Aryl;Building Blocks;C8;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Benzyl
Mol File:89-92-9.mol
2-Methylbenzyl bromide Structure
2-Methylbenzyl bromide Chemical Properties
Melting point 16-20 °C(lit.)
Boiling point 216-217 °C742 mm Hg(lit.)
density 1.381 g/mL at 25 °C(lit.)
refractive index n20/D 1.575(lit.)
Fp 180 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Light yellow
Water Solubility practically insoluble
Merck 14,10090
BRN 636333
CAS DataBase Reference89-92-9(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-(bromomethyl)-2-methyl-(89-92-9)
Safety Information
Hazard Codes C
Risk Statements 36/37/38-34-20/21/22
Safety Statements 26-36/37/39-45
RIDADR UN 1701 6.1/PG 2
WGK Germany 3
RTECS CY9039100
F 19
HazardClass 6.1
PackingGroup II
HS Code 29036990
Hazardous Substances Data89-92-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
alpha-Bromo-o-xylene English
SigmaAldrich English
ACROS English
ALFA English
2-Methylbenzyl bromide Usage And Synthesis
Chemical Propertiesclear yellow liquid
Uses1-(Bromomethyl)-2-methyl-benzene is a useful synthetic intermediate. It is used as a reagent in preparation of trisubstituted pyrazoles as novel hepatitis C virus entry inhibitors. It can also be used to synthesize polycyclic aromatic hydrocarbons (PAHs) such as 1,2:5,6-Dibenzanthracene (D417010).
2-Methylbenzyl bromide Preparation Products And Raw materials
Preparation Products2-Methylbenzylamine-->1,4-BIS(2-METHYLSTYRYL)BENZENE-->O-TOLYL-METHANESULFONYL CHLORIDE-->4-Methylbenzyl bromide-->1,2-Bis(cyanomethyl)benzene-->2-Methylbenzyl alcohol-->2-Methylbenzyl cyanide-->Benzoic acid, 3-hydroxy-5-[(2-methylphenyl)methoxy]-, methyl ester-->(2-METHYLBENZYL)PHOSPHONIC ACID DIETHYL ESTER
(3-CYANO-5-TRIFLUOROMETHYL)-METHYLBENZYL BROMIDE 4-FLUORO-3-METHYLBENZYL BROMIDE 3-METHYLBENZYL BROMIDE, [1-14C] 6-CHLORO-2-FLUORO-3-METHYLBENZYL BROMIDE Musk xylene 4-METHYLBENZYL BROMIDE BENZENESULFONYL CHLORIDE Isopropyl-α-[2-methylhydrazino]-p-toluamide (-)-2-[METHYLAMINO]-1-PHENYLPROPANE para-xylylenebis-(triphenylphosphonium bromide), 2-Phenyl-1-propene Clidinium bromide 5-FLUORO-2-(TRIFLUOROMETHYL)BENZYL BROMIDE 3-BENZYLOXY-4-METHYLBENZYL BROMIDE 2-CHLORO-6-FLUORO-3-METHYLBENZYL BROMIDE P-XYLYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE) 5-FLUORO-2-METHYLBENZYL BROMIDE Bromine 3-METHOXY-4-METHYLBENZYL BROMIDE
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