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| | ACETONE-D6 Basic information |
| Product Name: | ACETONE-D6 | | Synonyms: | Acetone-d6 + TMS (99:1 v/v), deuteration degree min. 99,8%, NMR spectroscopy grade, Spectrosol;Acetone-D6(D99.8%)+TMS(0.03%);Acetone-d6, packaged in 0.75ml ampoules, 100.0 atom % D, for NMR;Acetone-d6, packaged in 0.75 ml ampoules, 99.5 atom % D, for NMR;Acetone-d6, 99.8 atom % D, AcroSeal, for NMR;ACETONE-D6 DEUTERATION DEGREE MIN. 99.95;ACETONE-D6, 99.9 ATOM % D (CONTAINS 1% &;ACETONE-D6, "100.0" (MIN. 99.96 ATOM % D)(1pkg=10X1,0ml) | | CAS: | 666-52-4 | | MF: | C3D6O | | MW: | 64.12 | | EINECS: | 211-563-9 | | Product Categories: | Analytical Chemistry;NMR Spectrometry;Deuterated Compounds for NMR;High Resolution NMR;Aldrich 100% NMR Solvents for High Resolution;UV/Vis);Tubes and Accessories;Stable Isotopes;Spectroscopy Solvents (IR;Solvents for High Throughput NMR;Solvents;Solvent by Type;Solvent by Application;Routine NMR;NMR Solvents and Reagents;NMR Solvents;NMR;Labware;Acetone-d6;A;Acetone;Aldrich High Purity NMR Solvents for Routine NMR;Alphabetical Listings;High Throughput NMR | | Mol File: | 666-52-4.mol |  |
| | ACETONE-D6 Chemical Properties |
| Melting point | −93.8 °C(lit.) | | Boiling point | 55.5 °C(lit.) | | density | 0.872 g/mL at 25 °C(lit.) | | vapor density | 2 (vs air) | | vapor pressure | 14.39 psi ( 55 °C) | | refractive index | n20/D 1.355(lit.) | | Fp | 1 °F | | storage temp. | Store below +30°C. | | form | Liquid In Prescored Ampoules, (0.75Ml/ampoule) | | color | Colorless | | Specific Gravity | 0.872 | | PH | 5-6 (365g/l, H2O) | | explosive limit | 2.6-12.8%(V) | | Water Solubility | Soluble in water. | | BRN | 1702935 | | Stability: | Stable. Highly flammable. Readily forms explosive mixtures with air. Note low flashpoint and wide explosion limits. Incompatible with bases, oxidising agents, strong acids, reducing agents. Protect from moisture. | | CAS DataBase Reference | 666-52-4(CAS DataBase Reference) | | EPA Substance Registry System | Acetone-d6 (666-52-4) |
| Hazard Codes | F,Xi | | Risk Statements | 11-36-66-67 | | Safety Statements | 9-16-26-33-23 | | RIDADR | UN 1090 3/PG 2 | | WGK Germany | 3 | | F | 10-21 | | Autoignition Temperature | 465 °C DIN 51794 | | HS Code | 2845 90 10 | | HazardClass | 3 | | PackingGroup | II | | Toxicity | LD50 orally in Rabbit: 5800 mg/kg LD50 dermal Rabbit 20000 mg/kg |
| | ACETONE-D6 Usage And Synthesis |
| Chemical Properties | colourless liquid | | Uses | Acetone-d6 may be used as a deuterated solvent in the 1H NMR spectral studies of iodine containing radiopaque poly(methacrylate)copolymers. It may also be used as a source of deuterium atoms in the synthesis of labelled sterols. | | Uses | Acetone-d6 may be used as an internal standard to detect aldehydes and acetone in water by headspace-solid-phase microextraction and gas chromatography-mass spectrometry. | | Uses | Isotope labelled Acetone is a common organic building block in organic chemistry. | | Definition | ChEBI: A deuterated compound that is acetone in which all six hydrogen atoms are replaced by deuterium. | | General Description | Acetone-d6 can be prepared by reacting heavy water with propyne-d4 in the presence of mercury catalyst. |
| | ACETONE-D6 Preparation Products And Raw materials |
| Raw materials | FORMIC-D ACID, POTASSIUM SALT-->2-PROPANOLE-D7-->2-PROPANOL-D8-->ACETIC ACID-D4-->ACETYLENE-D2-->2-PROPANOL-1,1,1,3,3,3-D6-->2-Heptanone-->N,O-Dimethylhydroxylamine hydrochloride-->Acetophenone | | Preparation Products | 4-OXO-2,2,6,6-TETRAMETHYLPIPERIDINE-D16-1-OXYL |
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