TANTALUM ETHOXIDE

TANTALUM ETHOXIDE Basic information
Description Reference
Product Name:TANTALUM ETHOXIDE
Synonyms:ethanol,tantalum(5+)salt;TANTAL(V)-ETHOXID;TANTALUM PENTAETHOXIDE;TANTALUM(V) ETHOXIDE;TANTALUM ETHOXIDE;TANTALUM ETHYLATE;Tantalum(V) ethoxide, 99.98% metals basis;TANTALUM (V) ETHOXIDE (99.99+%-TA) SPECTRO
CAS:6074-84-6
MF:C10H25O5Ta
MW:406.25
EINECS:228-010-2
Product Categories:metal alkoxide;Catalysis and Inorganic Chemistry;Chemical Synthesis;Solution Deposition Precursors;Tantalum;TantalumMicro/Nanoelectronics;73: Tantalum;CVD and ALD Precursors by Metal;CVD and ALD Precursors Packaged for Deposition Systems;Micro &;Nanoelectronics;Vapor Deposition Precursors;Materials Science;Micro/NanoElectronics;New Products for Materials Research and Engineering;bc0001
Mol File:6074-84-6.mol
TANTALUM ETHOXIDE Structure
TANTALUM ETHOXIDE Chemical Properties
Melting point 21 °C(lit.)
Boiling point 155 °C0.01 mm Hg(lit.)
density 1.566 g/mL at 25 °C(lit.)
refractive index n20/D 1.487(lit.)
Fp 87 °F
storage temp. 2-8°C
solubility Soluble in organic solvents.
form liquid
Specific Gravity1.56
Water Solubility Decomposes in water. Soluble in organic solvents.
Sensitive Moisture Sensitive/Air Sensitive
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
BRN 3678999
CAS DataBase Reference6074-84-6(CAS DataBase Reference)
EPA Substance Registry SystemEthanol, tantalum(5+) salt (6074-84-6)
Safety Information
Hazard Codes C,F
Risk Statements 10-34
Safety Statements 16-26-36/37/39-45
RIDADR UN 2920 8/PG 2
WGK Germany 3
3-8-10-21
TSCA No
HazardClass 3
PackingGroup III
HS Code 2905190019
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TANTALUM ETHOXIDE Usage And Synthesis
DescriptionTantalum ethoxide can be used for the manufacture of tantalum (V) oxidethin-film materials using chemical vapor deposition, atomic layer deposition, and sol-gel processing. Those materials have applications in semiconductor, electrochromic and optical fields1,2,3. In research filed, it can be used for the synthesis of some novel compounds such as oxo-alkoxide-carboxylates like Ta4O4(OEt)8(OOCCH3)4 with special molecular structure2. It is also used to prepare tantalum oxide nanoparticles for the imaging cartilage4.
Reference
  1. Sukanya Murali, †, A. Anand Deshpande, and C. G. Takoudis. "Modeling of the Metalorganic Chemical Vapor Deposition of Tantalum Oxide from Tantalum Ethoxide and Oxygen." Industrial & Engineering Chemistry Research 44.16(2005): págs. 6387-6392.
  2. Dong, L. U., et al. "Synthesis Method and Application of Tantalum (Ⅴ) Ethoxide" Guangzhou Chemical Industry (2016).
  3. https://www.alfa.com/en/catalog/014643/
Chemical Propertiesclear colorless to almost colorless liquid or
UsesTantalum(V) ethoxide precursor is used to deposit ultra thin films of Tantalum oxide and other tantalum containing films by atomic layer deposition and chemical vapor deposition methods
UsesTantalum(V) ethoxide acts as a precursor used in the preparation of ultra thin films of tantalum oxide and other tantalum containing films, which finds application in semiconductors. It is also used to prepare tantalum oxide nanoparticles for the imaging cartilage.
General DescriptionTantalum(V) ethoxide Ta(OC2H5)5 is a tantalum alkoxide that can be used as a precursor in the preparation of tantalum oxide by chemical vapor deposition (CVD). It has excellent volatility and thermal stability. It can be synthesized by anodic oxidation of tantalum plate in anhydrous ethanol.
Purification MethodsPurify it by distillation under reduced pressure. It aggregates in *C6H6,EtOH, MeCN, pyridine and diisopropyl ether. [Bradley et al. J Chem Soc 726 1955, Bradley et al. J Chem Soc 5 1956, Beilstein 1 IV 1312.]
TANTALUM ETHOXIDE Preparation Products And Raw materials
TANTALUM PENTA-T-BUTOXIDE POTASSIUM TANTALUM ISOPROPOXIDE TANTALUM PENTA-I-BUTOXIDE TANTALUM TETRAETHOXIDE DIMETHYLAMINOETHOXIDE LITHIUM TANTALUM ETHOXIDE,Lithium tantalum ethoxide, 5% w/v in ethanol, 99.9% (metals basis) TANTALUM(V) TETRAETHOXIDE 2,4-PENTANEDIONATE TANTALUM(V) BUTOXIDE STRONTIUM TANTALUM ETHOXIDE BARIUM TANTALUM ISOPROPOXIDE STRONTIUM TANTALUM ISOPROPOXIDE STRONTIUM BIS[TANTALUM(PENTAETHOXIDE) (2-METHOXYETHOXIDE)] SODIUM TANTALUM ISOPROPOXIDE TANTALUM ETHOXIDE LITHIUM TANTALUM BUTOXIDE LITHIUM TANTALUM TERT-BUTOXIDE LITHIUM TANTALUM ISOPROPOXIDE TANTALUM (V) ISOPROPOXIDE TANTALUM PENTA-N-PROPOXIDE

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