meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Basic information
Uses
Product Name:meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane
Synonyms:meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane;1,3,5,7-TetraMethyl-6-phenyl-2,4,8-trioxa-6-phosphaadaMantane,99%;1,3,5,7-TetraMethyl-8-phenyl-2,4,6-trioxa-8-phosphaadaMantane, 99% MeCgPPh;1,3,5,7-TetraMethyl-2,4,8-trioxa-6-phenyl-6-phosphaadaMantane, 98% (MeCgPPh);1,3,5,7-TetraMethyl-6-phenyl-2,4,8-trioxa-6-phosphaadaMantane 97%;1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane;1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane, (MeCgPPh);1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane
CAS:97739-46-3
MF:C16H21O3P
MW:292.31
EINECS:
Product Categories:organophosphine ligand;Achiral Phosphine;Aryl Phosphine
Mol File:97739-46-3.mol
meCgPPh,  1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Structure
meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Chemical Properties
Melting point 106-111 °C
Boiling point 363.4±42.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color white
Sensitive air sensitive, moisture sensitive
Safety Information
Risk Statements 36/37/38
Safety Statements 26-37
WGK Germany 3
TSCA No
MSDS Information
meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Usage And Synthesis
UsesA bulky, robust, and electron-poor ligand that gives efficient rhodium hydroformylation and palladium cross-coupling catalysts.
Uses1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:
  • As a ligand to synthesize complexes for hydroformylation catalysis.
  • To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.

meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Preparation Products And Raw materials
Methyl methacrylate meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane 2,6-dimethyl-1,3-dioxan-4-ol BIS(HYDROXYMETHYL)PHENYLPHOSPHINE

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