|
| meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Basic information | Uses |
Product Name: | meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane | Synonyms: | meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane;1,3,5,7-TetraMethyl-6-phenyl-2,4,8-trioxa-6-phosphaadaMantane,99%;1,3,5,7-TetraMethyl-8-phenyl-2,4,6-trioxa-8-phosphaadaMantane, 99% MeCgPPh;1,3,5,7-TetraMethyl-2,4,8-trioxa-6-phenyl-6-phosphaadaMantane, 98% (MeCgPPh);1,3,5,7-TetraMethyl-6-phenyl-2,4,8-trioxa-6-phosphaadaMantane 97%;1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane;1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane, (MeCgPPh);1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane | CAS: | 97739-46-3 | MF: | C16H21O3P | MW: | 292.31 | EINECS: | | Product Categories: | organophosphine ligand;Achiral Phosphine;Aryl Phosphine | Mol File: | 97739-46-3.mol | |
| meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Chemical Properties |
Melting point | 106-111 °C | Boiling point | 363.4±42.0 °C(Predicted) | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | form | Powder | color | white | Sensitive | air sensitive, moisture sensitive |
Risk Statements | 36/37/38 | Safety Statements | 26-37 | WGK Germany | 3 | TSCA | No |
| meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Usage And Synthesis |
Uses | A bulky, robust, and electron-poor ligand that gives efficient rhodium hydroformylation and palladium cross-coupling catalysts.
| Uses | 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:
- As a ligand to synthesize complexes for hydroformylation catalysis.
- To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.
|
| meCgPPh, 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane Preparation Products And Raw materials |
|