Gold hydroxide

Gold hydroxide Basic information
Product Name:Gold hydroxide
Synonyms:Gold trihydroxide;GOLD(III) HYDROXIDE;GOLD HYDROXIDE;gold trihydrate;goldhydroxide(au(oh)3);Gold(III) hydroxide, 99.9%;GOLD (III) HYDROXIDE, 99.9% (CL < 100PPM);Gold(III) hydroxide, Au 79% min
CAS:1303-52-2
MF:AuH3O3
MW:247.99
EINECS:215-120-0
Product Categories:Gold Salts;Metal and Ceramic Science;Salts
Mol File:1303-52-2.mol
Gold hydroxide Structure
Gold hydroxide Chemical Properties
Melting point decomposes at ~100℃ [LID94]
form Powder
Water Solubility Insoluble in water.
Sensitive Light Sensitive
Merck 14,4523
Solubility Product Constant (Ksp)pKsp: 45.26
Stability:Stability May decompose upon exposure to light. Incompatible with strong oxidizing agents.
CAS DataBase Reference1303-52-2(CAS DataBase Reference)
EPA Substance Registry SystemGold hydroxide (Au(OH)3) (1303-52-2)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Gold hydroxide Usage And Synthesis
Chemical Propertiessolid
Physical propertiesBrown powder; decomposes at 100°C; insoluble in water; soluble in acid.
UsesIn gold-plating solutions; for decorating porcelains.
UsesSynthesis of gold hydroxide complexes with N-heterocyclic carbene has been reported. A variety of perfluoroaryls, N-heterocyclic and alkynyl compounds may be synthesized by reacting gold(III) hydroxide with C–H and N–H compounds and arylboronic acids. Potassium aurate may be prepared by heating auric hydroxide with conc. KOH. 3
Production MethodsGold(III) hydroxide is precipitated by mixing aqueous solutions of potassium auric chloride and sodium carbonate:2KAuCl4 + 3Na2CO3 + 3H2O → 2Au(OH)3 + 6NaCl + 2KCl + 3CO2
The product usually contains about three molecules of water of crystallization. It may alternatively be prepared by adding caustic soda solution to sodium auric cyanide: NaAu(CN)4 + 3NaOH → Au(OH)3 + 4NaCN.
Gold hydroxide Preparation Products And Raw materials
Cobalt(II) hydroxide INDIUM HYDROXIDE Magnesium hydroxide GOLD (III) ACETATE Ammonium hydroxide Hydrogen tetrachloroaurate(III) trihydrate GOLD (III) 2-ETHYLHEXANOATE Hydroxide Digold trioxide Gold hydroxide Hydrogen peroxide Barium hydroxide Cobalt hydroxide Black-Gold Lithium hydroxide monohydrate Sodium hydroxide GOLD CATALASE

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