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| 1-(TRIISOPROPYLSILYL)PYRROLE Basic information |
| 1-(TRIISOPROPYLSILYL)PYRROLE Chemical Properties |
Boiling point | 78 °C0.4 mm Hg(lit.) | density | 0.904 g/mL at 25 °C(lit.) | refractive index | n20/D 1.492(lit.) | Fp | 224 °F | storage temp. | Inert atmosphere,2-8°C | pka | -2.55±0.70(Predicted) | form | clear liquid | color | Colorless to Almost colorless | Specific Gravity | 0.904 | Water Solubility | Not miscible in water. | Sensitive | Moisture Sensitive | Hydrolytic Sensitivity | 7: reacts slowly with moisture/water | BRN | 3540663 | CAS DataBase Reference | 87630-35-1(CAS DataBase Reference) |
Hazard Codes | Xn | Risk Statements | 20-22-36 | Safety Statements | 24/25-26 | WGK Germany | 3 | HS Code | 2933998090 |
| 1-(TRIISOPROPYLSILYL)PYRROLE Usage And Synthesis |
Uses | 1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc). | Uses | 1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of:
- ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate
- heterocyclic base, 3-nitropyrrole
- 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole
| General Description | 1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc). |
| 1-(TRIISOPROPYLSILYL)PYRROLE Preparation Products And Raw materials |
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