1-(TRIISOPROPYLSILYL)PYRROLE

1-(TRIISOPROPYLSILYL)PYRROLE Basic information

Product Name:	1-(TRIISOPROPYLSILYL)PYRROLE
Synonyms:	1-TRIISOPROPYLSILANYL-1H-PYRROLE;1-(TRIISOPROPYLSILYL)PYRROLE;N-TRIISOPROPYLSILYL PYRROLE;tri(propan-2-yl)-(1-pyrrolyl)silane;1-[tris(propan-2-yl)silyl]-1H-pyrrole;1-(Triisopropylsilyl)pyrrole 95%;1H-Pyrrole, 1-[tris(1-Methylethyl)silyl]-;1-(Triisopropylsilyl)-1H-pyrrole
CAS:	87630-35-1
MF:	C13H25NSi
MW:	223.43
EINECS:
Product Categories:	Pyrrole&Pyrrolidine&Pyrroline;Functional Materials;Pyrroles (for Conduting Polymer Research);Reagents for Conducting Polymer Research;Si (Classes of Silicon Compounds);Si-N Compounds;Trimethylsilylazide, etc.;Building Blocks;Heterocyclic Building Blocks;Pyrroles
Mol File:	87630-35-1.mol

1-(TRIISOPROPYLSILYL)PYRROLE Chemical Properties

Boiling point	78 °C0.4 mm Hg(lit.)
density	0.904 g/mL at 25 °C(lit.)
refractive index	n20/D 1.492(lit.)
Fp	224 °F
storage temp.	Inert atmosphere,2-8°C
pka	-2.55±0.70(Predicted)
form	clear liquid
color	Colorless to Almost colorless
Specific Gravity	0.904
Water Solubility	Not miscible in water.
Sensitive	Moisture Sensitive
Hydrolytic Sensitivity	7: reacts slowly with moisture/water
BRN	3540663
CAS DataBase Reference	87630-35-1(CAS DataBase Reference)

Safety Information

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

1-(TRIISOPROPYLSILYL)PYRROLE Usage And Synthesis

Uses	1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
Uses	1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of: ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate heterocyclic base, 3-nitropyrrole 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole
General Description	1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br⁺, I⁺,NO₂⁺,etc).

1-(TRIISOPROPYLSILYL)PYRROLE Preparation Products And Raw materials

Preparation Products

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