COBALT(II) BROMIDE HYDRATE

COBALT(II) BROMIDE HYDRATE Basic information
Product Name:COBALT(II) BROMIDE HYDRATE
Synonyms:Cobalt(II) broMide hydrate 100GR;Cobalt bromide hydrate;COBALT(II) BROMIDE 6 H2O;COBALT(II) BROMIDE HYDRATE;COBALT(II) BROMIDE HYDRATE ISO 9001:2015 REACH;OBALT(II) BROMIDE HYDRATE;Cobalt(ll) bromide hydrate
CAS:85017-77-2
MF:Br2CoH2O
MW:236.76
EINECS:678-761-9
Product Categories:metal halide
Mol File:85017-77-2.mol
COBALT(II) BROMIDE HYDRATE Structure
COBALT(II) BROMIDE HYDRATE Chemical Properties
Melting point 47-48°C
density 2,462 g/cm3
form Crystals
Specific Gravity~2.462
color Violet
Water Solubility Soluble in water.
Sensitive Hygroscopic
Merck 14,2435
Exposure limitsACGIH: TWA 0.02 mg/m3
InChIKeyMOTZAWYGLXXRSO-UHFFFAOYSA-L
CAS DataBase Reference85017-77-2
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-28-36/37/39-45
RIDADR UN 3077 9 / PGIII
WGK Germany 3
RTECS GF9595000
3
TSCA Yes
HS Code 28275900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
COBALT(II) BROMIDE HYDRATE Usage And Synthesis
Chemical PropertiesRed violet crystal.
UsesHygrometers, catalystsCobalt(II) bromide hydrate is mainly used as a catalyst in organic synthesis, like C-metal, C-heteroatom and C-C bond formations, addition to unsaturated bonds, cyclizations, polymerization, oxidations reductions and carbonylations. It reacts with ammonia to form coordination compound bromopentaamminecobalt(III) bromide. It reacts with triphenylphosphine and form complexes of cobalt(II) bromide, which used as a catalyst in organic synthesis.
Purification MethodsCrystallise it from water (1mL/g) by partial evaporation in a desiccator. The anhydrous salt is soluble in EtOH, Me2CO, MeOAc to form blue-coloured solutions. [Glemser in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1517 1965.]
COBALT(II) BROMIDE HYDRATE Preparation Products And Raw materials
Nickel chloride Cupric nitrate Potassium pyrophosphate IRON (III) BROMIDE Lead fluoride Silver chloride Cupric fluoride Sodium sulfite Potassium Phosphate Monobasic COBALT(II) OXALATE DIHYDRATE Copper(II) sulfate pentahydrate ZINC TELLURIDE Titanium tetrachloride MANGANESE(II) ACETATE IODINE MONOBROMIDE Sodium carbonate COBALT(II) BROMIDE COBALT BROMIDE, HEXAHYDRATE

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