ChemicalBook Product Catalog Chemical Reagents Silane reagent 2-(ALLYLDIMETHYLSILYL)PYRIDINE

2-(ALLYLDIMETHYLSILYL)PYRIDINE

2-(ALLYLDIMETHYLSILYL)PYRIDINE Basic information
Product Name:2-(ALLYLDIMETHYLSILYL)PYRIDINE
Synonyms:2-(ALLYLDIMETHYLSILYL)PYRIDINE, 90%;Allyldimethyl(2-pyridyl)silane;(2-pyridyl)allyldimethylsilane;dimethyl-prop-2-enyl-pyridin-2-ylsilane;Pyridine, 2-(dimethyl-2-propen-1-ylsilyl)-;imethyl-prop-2-enyl-pyridin-2-ylsilane
CAS:118722-54-6
MF:C10H15NSi
MW:177.32
EINECS:
Product Categories:Heterocyclic Compounds
Mol File:118722-54-6.mol
2-(ALLYLDIMETHYLSILYL)PYRIDINE Structure
2-(ALLYLDIMETHYLSILYL)PYRIDINE Chemical Properties
Boiling point 104-105°C / 18
density 0.913 g/mL at 25 °C
refractive index n20/D 1.5046
Fp 71 °C
storage temp. 2-8°C
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
RIDADR UN 3334
WGK Germany 3
MSDS Information
2-(ALLYLDIMETHYLSILYL)PYRIDINE Usage And Synthesis
Uses2-(Allyldimethylsilyl)pyridine can be used as a pyridyl transfer reagent to prepare substituted pyridine derivatives by reacting with various aryl iodides in the presence of a palladium catalyst and silver(I) oxide activator. It can also be utilized as a coupling reagent in the allylation of carbonyl compounds using a copper catalyst.
2-(ALLYLDIMETHYLSILYL)PYRIDINE Preparation Products And Raw materials
Raw materialsALLYLDIMETHYLCHLOROSILANE-->2-Bromopyridine
(TERT-BUTYLDIMETHYLSILYLOXY)ACETALDEHYDE 2-(Trimethylsilyl)pyridine 2-(DIMETHYLSILYL)PYRIDINE ALLYLDIMETHYLSILANE 2-(ALLYLDIMETHYLSILYL)PYRIDINE
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