ChemicalBook Product Catalog Inorganic chemistry Inorganic salts Cyanide, hydroxide and hydrogen complexes TETRABUTYLAMMONIUM CYANIDE

TETRABUTYLAMMONIUM CYANIDE

TETRABUTYLAMMONIUM CYANIDE Basic information
Product Name:TETRABUTYLAMMONIUM CYANIDE
Synonyms:TETRABUTYLAMMONIUM CYANIDE;1-Butanaminium, N,N,N-tributyl-, cyanide;Tetrabutylammonium cyanide technical, >=80%;Tetrabutylaminium·cyanide;TetrabutylaMMoniuM cyanide 95%;N,N,N-Tributyl-1-butanaminium cyanide (1:1);tetrabutylazanium:cyanide;n,n,n-tributyl-1-butanaminiucyanide
CAS:10442-39-4
MF:C17H36N2
MW:268.48
EINECS:233-926-0
Product Categories:Ammonium Salts;Greener Alternatives: Catalysis;Phase Transfer Catalysts
Mol File:10442-39-4.mol
TETRABUTYLAMMONIUM CYANIDE Structure
TETRABUTYLAMMONIUM CYANIDE Chemical Properties
Melting point 89-92 °C(lit.)
solubility Methanol (Slightly), Water (Slightly)
form Solid
color Pale Yellow to Pale Beige
BRN 3598808
Stability:Hygroscopic
EPA Substance Registry System1-Butanaminium, N,N,N-tributyl-, cyanide (10442-39-4)
Safety Information
Hazard Codes T+,N
Risk Statements 26/27/28-32-50/53
Safety Statements 7-28-29-45-60-61
RIDADR UN 2811 6.1/PG 2
WGK Germany 3
F 3-10
HazardClass 6.1(b)
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
TETRABUTYLAMMONIUM CYANIDE Usage And Synthesis
UsesTetrabutylammonium cyanide is commonly used as a catalyst for the synthesis of organic compounds such as multisubstituted dihydrofurans and pyrrolo[2,?1-?a]?isoquinolines.
UsesTetrabutylammonium cyanide (TBACN) can be used as a source of cyanide ion for colorimetric studies.
It can be employed as a reactant in the preparation of:
  • Tetrabutylammonium fluoride (TBAF), which can be used to remove silyl ether protecting groups.
  • Rhenium-based single-chain magnets, (DMF)4MReCl4(CN)2 (M = Mn, Fe, Co, Ni).
  • Phosphorescent blue light-emitting anionic iridium complexes.

TETRABUTYLAMMONIUM CYANIDE Preparation Products And Raw materials
Preparation ProductsTetrabutylammonium iodide-->2,4-Dichlorophenylacetonitrile-->4-HYDROXY-3-METHOXYPHENYLACETONITRILE-->OCTANENITRILE-->3-NITROPHENYLACETONITRILE-->2-Cyano-3-chloro-5-(trifluoromethyl)-pyridine-->4-Biphenylacetonitrile-->4-Cyanotetrahydro-4H-pyran-->5,5-DIPROPYL-IMIDAZOLIDINE-2,4-DIONE
Tetrabutylammonium iodide Tetrabutylammonium tribromide Tetrabutylammonium hexafluorophosphate Borane tert-butylamine complex TETRAETHYLAMMONIUM CYANIDE Sodium erythorbate ammonium cyanide TETRABUTYLAMMONIUM CYANIDE
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