1,3-Bis(bromomethyl)benzene

1,3-Bis(bromomethyl)benzene Basic information
Product Name:1,3-Bis(bromomethyl)benzene
Synonyms:m-Xylylene Bromide m-Xylylene Dibromide 1,3-Bis(bromomethyl)benzene;1,3-bis(bromomethyl)-benzen;a,a'-m-Xylene dibromide;alpha,alpha'-Dibromo-meta-xylene;benzene,1,3-bis(bromomethyl)-;m-(Bromomethyl)benzyl bromide;m-alpha,alpha'-Dibromoxylene;m-Bis(bromomethyl)benzene
CAS:626-15-3
MF:C8H8Br2
MW:263.96
EINECS:210-931-6
Product Categories:Aryl;Building Blocks;C8;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Halides;Aromatic Halides (substituted)
Mol File:626-15-3.mol
1,3-Bis(bromomethyl)benzene Structure
1,3-Bis(bromomethyl)benzene Chemical Properties
Melting point 74-77 °C(lit.)
Boiling point 135-140 °C20 mm Hg(lit.)
density 1.9590
refractive index 1.6113 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility dioxane: 0.1 g/mL, clear, colorless
form Crystalline Powder and Chunks
color White to brown
Water Solubility Insoluble in water.
BRN 971085
CAS DataBase Reference626-15-3(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1,3-bis(bromomethyl)-(626-15-3)
EPA Substance Registry System1,3-Bis(bromomethyl)benzene (626-15-3)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-43
Safety Statements 26-36/37
RIDADR UN 3448 6.1/PG 2
WGK Germany 3
8-19-21
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29036990
MSDS Information
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1,3-Bis(bromomethyl)benzene Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses1,3-Bis(bromomethyl)benzene has been used in preparation of four novel dinuclear half-titanocenes with meta - and ortho xylene bridges as new metallocenes 1 . It was used in the synthesis of dissymmetrical bis -macrocyclic salt 2 .
UsesIt is used in preparation of four novel dinuclear half-titanocenes with?meta- and?orthoxylene bridges as new metallocenes. It was used in the synthesis of dissymmetrical bis-macro cyclic salt.
General Descriptionα,α′-Dibromo-m-xylene can cross-link and cyclize peptides containing two cysteine residues.
Purification MethodsCrystallise it from acetone or *benzene, and fractionally distil it under vacuum. [Wenner Org Chem 17 527 1952, Beilstein 5 H 374, 5 I 184, 5 II 294, 5 III 839, 5 IV 946.]
1,3-Bis(bromomethyl)benzene Preparation Products And Raw materials
Preparation Products1,3-BIS(DI-T-BUTYLPHOSPHINOMETHYL)BENZENE-->3-Methylbenzyl bromide-->1,3-bis((1H-imidazol-1-yl)methyl)benzene-->1,3-BENZENEDIMETHANETHIOL
Xylene 2-Aminobenzylchloride alpha-Chloro-o-fluorotoluene Musk xylene 2,4-DIBROMOPENTANE Decabromodiphenyl Ethane 4-Bromomethylbenzoic acid 2-Chlorobenzyl chloride 2-Methylbenzyl chloride Benzyl bromide Benzene 2,2-Bis(bromomethyl)propane-1,3-diol Benzhydrylamine 1,2-Dibromopropane 1,3-Dibromo-5,5-dimethylhydantoin 2-(Chloromethyl)benzonitrile 1,3-Bis(bromomethyl)benzene Diethylstilbestrol

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