6-Chlorohex-1-ene

6-Chlorohex-1-ene Basic information

Product Name:	6-Chlorohex-1-ene
Synonyms:	6-chloro-1-hexen;6-CHLORO-1-HEXENE;6-chlorohex-1-ene;5-Hexenyl chloride;6-Chloro-1-hexene,97%;Chloro-1-hex;6-CHLORO-1-HEXENE, 97%6-CHLORO-1-HEXENE, 97%6-CHLORO-1-HEXENE, 97%6-CHLORO-1-HEXENE, 97%;1-Hexene, 6-chloro-
CAS:	928-89-2
MF:	C6H11Cl
MW:	118.6
EINECS:	213-186-5
Product Categories:	Alkenyl;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:	928-89-2.mol

6-Chlorohex-1-ene Chemical Properties

Boiling point	135-136 °C (lit.)
density	0.896 g/mL at 25 °C (lit.)
refractive index	n20/D 1.438(lit.)
Fp	84 °F
storage temp.	Flammables area
form	Liquid
Specific Gravity	0.907
color	Clear colorless to light yellow
Stability:	Stable. Flammable. Incompatible with strong oxidizing agents.
EPA Substance Registry System	1-Hexene, 6-chloro- (928-89-2)

Safety Information

Hazard Codes	Xi
Risk Statements	10-36/37/38
Safety Statements	16-26-36-37/39
RIDADR	UN 3295 3/PG 2
WGK Germany	3
TSCA	Yes
HazardClass	3
HS Code	29032900

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

6-Chlorohex-1-ene Usage And Synthesis

Chemical Properties	colourless liquid
Uses	6-Chloro-1-hexene is used as pharmaceutical intermediate.
General Description	6-Chloro-1-hexene is an ω-chloro-1-alkene. It reacts with β-substituted imines in the presence of a rhodium catalyst to afford tri- and tetra-substituted imines. It undergoes cross-coupling reaction in the presence of copper(II) chloride and 1-phenylpropyne.

6-Chlorohex-1-ene Preparation Products And Raw materials

Raw materials	5-Hexen-1-ol, 1-(4-methylbenzenesulfonate)-->6-CHLORO-1-HEXYNE-->1-CHLORO-3-IODOPROPANE-->5-HEXENOIC ACID-->Diethyl malonate-->5-Hexen-1-ol-->Allylmagnesium chloride-->Carbon tetrachloride-->1-Bromo-3-chloropropane-->Allyl bromide
Preparation Products	1-Chlorohexane-->1,5-HEXADIENE-->1-Hexene-->Hexane

7,7-Dichlorobicyclo[3.2.0]hept-2-en-6-one CHLORDANE HEPTENOPHOS 6-Chlorohexanol 1-Hexene Chloroacetic acid TRICHLOROHEXAHYDRO-BETA-NAPHTHOL Difluorochloromethane chlorempenthrin Cholesteryl chloride TIMTEC-BB SBB008460 METHYL 3,3-DICHLORO-2-[(2,2-DICHLORO-1-PHENYLCYCLOPROPYL)METHYL]ACRYLATE Allyl chloroformate GAMMA-CHLORDAN Epichlorohydrin 6-Chlorohex-1-ene Diethylstilbestrol Allyl chloride

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