ChemicalBook Product Catalog Chemical Reagents Organic reagents Cyanide / nitrile ETHYL 2-CYANO-3-METHYLCROTONATE

ETHYL 2-CYANO-3-METHYLCROTONATE

ETHYL 2-CYANO-3-METHYLCROTONATE Basic information
Product Name:ETHYL 2-CYANO-3-METHYLCROTONATE
Synonyms:Crotonic acid, 2-cyano-3-methyl-, ethyl ester;Ethyl isopropylidene(cyano)acetate;TIMTEC-BB SBB007715;ETHYL 2-CYANO-3-METHYLCROTONATE;ETHYL 2-CYANO-3-METHYL-2-BUTENOATE;Ethyl 2-cyano-3-methylbutanoate;2-cyano-3-methylcrotonic acid ethyl ester;Ethyl 2-cyano-3-methyl-2-butanoate
CAS:759-58-0
MF:C8H11NO2
MW:153.18
EINECS:
Product Categories:Small molecule;C8 to C9;Carbonyl Compounds;Esters
Mol File:759-58-0.mol
ETHYL 2-CYANO-3-METHYLCROTONATE Structure
ETHYL 2-CYANO-3-METHYLCROTONATE Chemical Properties
Melting point ca 20℃
Boiling point 98-99 °C/1 mmHg (lit.)
density 1.014 g/mL at 25 °C (lit.)
refractive index n20/D 1.464(lit.)
Fp 224 °F
BRN 507839
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39
RIDADR 3276
WGK Germany 3
HazardClass 6.1
PackingGroup III
HS Code 29269095
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
ETHYL 2-CYANO-3-METHYLCROTONATE Usage And Synthesis
Chemical Propertiesclear colorless to slightly yellow liquid
Synthesis Reference(s)Journal of the American Chemical Society, 71, p. 3418, 1949 DOI: 10.1021/ja01178a044
General DescriptionEthyl 2-cyano-3-methyl-2-butenoate, a highly activated acceptor, undergoes the phospha-Michael reaction upon trituration of the reagents at room temperature.
ETHYL 2-CYANO-3-METHYLCROTONATE Preparation Products And Raw materials
DIETHYL DICYANOFUMARATE, 97 ETHYL 2-NITRILO-2-(2-OXOINDOLIN-3-YLIDENE)ACETATE CYANO-[1,2,5-TRIMETHYL-PIPERIDIN-(4Z)-YLIDENE]-ACETIC ACID ETHYL ESTER Octocrylene Etocrilene ETHYL 2-CYANO-2-CYCLOHEPTYLIDENACETATE ethyl (1-benzyl-2-oxo-1,2-dihydro-3H-indol-3-ylidene)(cyano)acetate TIMTEC-BB SBB000822 ETHYL 2-(1-BENZYL-4-PIPERIDINYLIDENE)-2-CYANOACETATE CYANO-CYCLOHEXYLIDENE-ACETIC ACID ETHYL ESTER ETHYL 2-CYANO-3-PHENYL-2-BUTENOATE ETHYL 2-CYANO-3-(2-METHOXYPHENYL)BUT-2-ENOATE CYANO-[2,2-DIMETHYL-TETRAHYDRO-PYRAN-(4Z)-YLIDENE]-ACETIC ACID ETHYL ESTER AKOS BB-9963 ETHYL CYANO(CYCLOPENTYLIDENE)ACETATE ETHYL 2-(1-BENZYLHEXAHYDROPYRIDINIUM-4-YLIDEN)-2-CYANOACETATE CHLORIDE ETHYL 2-CYANO-3,4-DIMETHYL-2-PENTENOATE ETHYL 2-CYANO-3-METHYLCROTONATE
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