ChemicalBook Product Catalog Biochemical Engineering Amino Acids and Derivatives Alanine derivatives Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate

Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate

Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate Basic information
Product Name:Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate
Synonyms:N-[1-(S)-ETHOXYCARBONYL-3-PHENYLPROPYL]-N-CARBOXY-L-ALANINE ANHYDRIDE (NEPA-NCA);ECPPA-NCA;ENALAPRIL MALEATE INTERMEDIATES;N-(1-(S)-(+)-ETHOXYCARBONYL-3-PHENYLPRO&;N-[1-(S)-ETHOXYCARBONYL-3-PHENYLPROPYL]-L-ALANINE -N-CARBOXYANHYDRIDE(INTERMEDIATE OF ENALAPRIL);n-[1-(s)-(ethoxycarbonyl)-3-phenylpropyl]-1-alanylcarboxy anhydride;N-(1-(S)-Ethoxy Carbonyl-3-Phenylpropyl)-L-Alanine-N-carboxyanhydried;EPAL-carboxanhydride
CAS:84793-24-8
MF:C16H19NO5
MW:305.33
EINECS:212-344-0
Product Categories:(intermediates of enalapril);Alanine Derivatives;Peptide Synthesis;Unnatural Amino Acid Derivatives
Mol File:84793-24-8.mol
Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate Structure
Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate Chemical Properties
Melting point 69-73 °C(lit.)
alpha 36.5 º (c=1, CHCl3)
Boiling point 414.8±55.0 °C(Predicted)
density 1.223±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Store in freezer, under -20°C
pka-2.40±0.40(Predicted)
optical activity[α]20/D +36.5°, c = 1 in chloroform
BRN 5608080
CAS DataBase Reference84793-24-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-43-41
Safety Statements 22-24/25-36-26-37/39-24
WGK Germany 3
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate Usage And Synthesis
Chemical PropertiesWhite powder
UsesN-[1-(S)-Ethoxycarbonyl-3-phenylpropyl]-L-alanine-N-carboxyanhydride is an impurity of Enalapril (E555250), an?antihypertensive and an angiotensin-converting enzyme (ACE) inhibitor.
Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate Preparation Products And Raw materials
Preparation ProductsRamipril-->(2R,3aR,6aR)-Ramipril-->N-[(S)-(+)-1-(Ethoxycarbonyl)-3-phenylpropyl]-L-alanine
(αS)-Cyclohexanebutanoic Acid α-[[(1S)-1-Carboxyethyl]aMino] cyclohexanebutanoic Acid α-Ethyl Ester Enalapril diketopiperazine (R,S,S)-Enalapril ACA Phenprobamate Methyl 2,5-OXAZOLIDINEDIONE Lisinopril Dihydrate EC 2.6.1.2 3-(2-HYDROXYETHYL)-2-OXAZOLIDINONE L-Homophenylalanine ethyl ester N-[(S)-1-Carbethoxy-1-butyl]-(S)-alanine Kresoxim-methyl L-β-Homophenylalanine, HPLC 98% (S)-4-Methyl-2,5-oxazolidonedione 2-(3-OXAZOLIDINE)ETHANOL (2-OXO-1,3-OXAZOLIDIN-3-YL)ACTETIC ACID Ethyl (S)-2-[(S)-4-methyl-2,5-dioxo-1,3-oxazolidin-3-yl]-4-phenylbutyrate
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