ChemicalBook Product Catalog Chemical Reagents Organic reagents aliphatic ketones 2,2-DIMETHYLCYCLOHEXANONE

2,2-DIMETHYLCYCLOHEXANONE

2,2-DIMETHYLCYCLOHEXANONE Basic information
Product Name:2,2-DIMETHYLCYCLOHEXANONE
Synonyms:2,2-Dimethyl-1-cyclohexanone;6,6-Dimethylcyclohexanone;2,2-Dimethylcyclohexanone ,93%;2,2-Dimethylcyclohexanone 92%;2,2-DIMETHYLCYCLOHEXANONE;Tretinoin Related Compound 2;2,2-dimethylcyclohexan-1-one;Cyclohexanone, 2,2-dimethyl-
CAS:1193-47-1
MF:C8H14O
MW:126.2
EINECS:
Product Categories:C7 to C8;Carbonyl Compounds;Ketones
Mol File:1193-47-1.mol
2,2-DIMETHYLCYCLOHEXANONE Structure
2,2-DIMETHYLCYCLOHEXANONE Chemical Properties
Melting point -20 °C (lit.)
Boiling point 169-170 °C/768 mmHg (lit.)
density 0.912 g/mL at 25 °C (lit.)
refractive index n20/D 1.448(lit.)
Fp 122 °F
storage temp. Sealed in dry,Room Temperature
solubility soluble in Chloroform, Dichloromethane
form Liquid
color Clear colorless to yellow
Safety Information
Risk Statements 10
Safety Statements 16
RIDADR UN 1224 3/PG 3
WGK Germany 3
HazardClass 3.2
PackingGroup III
HS Code 29142900
MSDS Information
ProviderLanguage
SigmaAldrich English
2,2-DIMETHYLCYCLOHEXANONE Usage And Synthesis
Uses2,2-Dimethylcyclohexanone may be used in the preparation of 6,6-dimethyl-1-vinylcyclohexene.
Synthesis Reference(s)The Journal of Organic Chemistry, 27, p. 1615, 1962 DOI: 10.1021/jo01052a031
Tetrahedron, 33, p. 2737, 1977 DOI: 10.1016/0040-4020(77)80265-2
Tetrahedron Letters, 24, p. 1341, 1983 DOI: 10.1016/S0040-4039(00)81651-2
General Description2,2-Dimethylcyclohexanone is a sterically hindered ketone. Mg-TiCl4-catalyzed CH2-transfer reaction of 2,2-dimethylcyclohexanone with CH2Cl2 is reported.
2,2-DIMETHYLCYCLOHEXANONE Preparation Products And Raw materials
Raw materialsToluene-->Sodium hydride-->Iodomethane-->2-Methylcyclohexanone
Preparation Products3,3-Dimethylcyclohexanone-->2,2-dimethylcyclohexane-1-carboxylic acid
WIELAND-MIESCHER KETONE 7-(BROMOMETHYL)-1,7-DIMETHYLBICYCLO[2.2.1]HEPTANE-2,3-DIONE 2-OXO-1,1,3,3-CYCLOHEXANETETRAPROPIONIC ACID HELVOLIC ACID FROM CEPHALOSPORIUM*CAERULENS 3-hydroxy-2-({4-nitrophenyl}sulfanyl)-5,5-dimethylcyclohexanone 3-TRIFLUOROACETYL-D-CAMPHOR 2,2,6,6-TETRAMETHYLCYCLOHEXANONE (+)-CAMPHORCARBOXYLIC ACID (1R)-(-)-10-CAMPHORSULFONIC ACID, AMMONIUM SALT colocynthin (R)-(+)-2-(2'-CARBOMETHOXYETHYL)-2-METHYLCYCLOHEXANONE HECOGENIN ACETATE AKOS BB-9893 3-(HEPTAFLUOROBUTYRYL)-I-CAMPHOR R(-)-8A-METHYL-3,4,8,8A-TETRAHYDRO-1,6(2H,7H)-NAPHTHALENEDIONE (+)-Camphor Bromide HEXAMETHYLCYCLOHEXANE-1,3,5-TRIONE (+)-CAMPHORCARBOXYLIC ACID ETHYL ESTER
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