METHYL ALPHA-CHLOROACRYLATE

METHYL ALPHA-CHLOROACRYLATE Basic information
Product Name:METHYL ALPHA-CHLOROACRYLATE
Synonyms:METHYL-A-CHLOROACRYLATE;METHYL ALPHA-CHLOROACRYLATE;METHYL CHLOROACRYLATE;Methyl alpha-chloroacrylate, stabilized with hydroquinone, 98+%;Methyl alpha-chloroacrylate, 98+%, stabilized with hydroquinone;Methyl alpha-chloroacrylate, stabilized with hydroquinone, 99% 25GR;Methyl 2-Chloroacrylate (stabilized with HQ);Methyl alpha-chloroacrylate, 99%, stabilized
CAS:80-63-7
MF:C4H5ClO2
MW:120.53
EINECS:201-298-7
Product Categories:monomer
Mol File:80-63-7.mol
METHYL ALPHA-CHLOROACRYLATE Structure
METHYL ALPHA-CHLOROACRYLATE Chemical Properties
Melting point -37 °C
Boiling point 52 °C (50 mmHg)
density 1.189
refractive index 1.442-1.444
Fp 33 °C
storage temp. Keep in dark place,Inert atmosphere,2-8°C
form Liquid
color Clear colorless to slightly brown
EPA Substance Registry SystemMethyl 2-chloroacrylate (80-63-7)
Safety Information
Hazard Codes T+
Risk Statements 34-26-24/25-10
Safety Statements 45-38-36/37/39-26-16
RIDADR 2927
HazardClass 6.1(a)
PackingGroup II
HS Code 29161995
Hazardous Substances Data80-63-7(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
METHYL ALPHA-CHLOROACRYLATE Usage And Synthesis
Chemical PropertiesMethyl 2-chloroacrylate is a colorless liquid.
Chemical Propertiesclear colorless to pale yellow liquid
UsesMethyl 2-Chloroacrylate is used as a reagent in various coupling reactions.
General DescriptionColorless liquid. Used to make acrylic high polymer with properties closely resembling those of polymethylmethacrylate. Monomer for specialty polymers (e.g., aircraft glazing).
Air & Water ReactionsInsoluble in water.
Reactivity ProfileMETHYL ALPHA-CHLOROACRYLATE is sensitive to prolonged exposure to light, moisture and heat. METHYL ALPHA-CHLOROACRYLATE is incompatible with oxidizers and polymerizers.
Health HazardMETHYL ALPHA-CHLOROACRYLATE is a skin, eye, and lung irritant. The least trace on skin raises large blisters. It is also a respiratory poison; breathing the vapors can cause pulmonary edema.
Fire HazardFlash point data for METHYL ALPHA-CHLOROACRYLATE are not available; however, METHYL ALPHA-CHLOROACRYLATE is probably combustible.
Potential ExposureUsed to make acrylic high polymer with properties closely resembling those of polymethylmethacrylate. Monomer for specialty polymers e.g., aircraft glazing). Corrosive. Lacrimator.
ShippingUN2929 Toxic liquids, flammable, organic, n.o.s., Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard, 3-Flammable liquid, Technical Name Required.
Incompatibilitiesapor may form explosive mixture with air. May hydrolyze upon contact with moisture. Incompatible with nitrates. Methyl 2-chloroacrylate is sensitive to prolonged exposure to light, moisture and heat. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and polymerizers. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur). May be a polymerization hazard
2,2'-BIPYRIDINE-4-CARBALDEHYDE METHYL 5-CHLORO-3-[(2,3,3-TRICHLOROACRYLOYL)OXY]THIOPHENE-2-CARBOXYLATE 3-CHLORO-5-(CHLOROMETHYL)-5-METHYL-4-PHENYL-2,5-DIHYDROFURAN-2-ONE haloxon 4-((3,5-DIMETHYL-4-[(2,3,3-TRICHLOROACRYLOYL)OXY]PHENYL)SULFONYL)-2,6-DIMETHYLPHENYL 2,3,3-TRICHLOROACRYLATE 4-((4-[(2,3,3-TRICHLOROACRYLOYL)OXY]PHENYL)SULFONYL)PHENYL 2,3,3-TRICHLOROACRYLATE 4-[5-(ALLYLTHIO)-1H-1,2,3,4-TETRAAZOL-1-YL]PHENYL 2,3,3-TRICHLOROACRYLATE 2-([5-(TRIFLUOROMETHYL)-2-PYRIDYL]SULFONYL)ETHYL 2,3,3-TRICHLOROACRYLATE CHLOROMALEIC ACID ANHYDRIDE Dichloromaleic anhydride 3-CHLORO-4-(DICHLOROMETHYL)-5-HYDROXY-2(5H)-FURANONE Coumaphos METHYL 4-BROMO-3-[(2,3,3-TRICHLOROACRYLOYL)OXY]THIOPHENE-2-CARBOXYLATE 3-(ACETYLAMINO)PHENYL 2,3,3-TRICHLOROACRYLATE METHYL 3-[(2,3,3-TRICHLOROACRYLOYL)OXY]THIOPHENE-2-CARBOXYLATE 3-OXO-2,3-DIHYDROBENZO[B]FURAN-6-YL 2,3,3-TRICHLOROACRYLATE ETHYL ALPHA-CHLOROACRYLATE 5-[(2,3,3-TRICHLOROALLANOYL)OXY][1,1'-BIPHENYL]-2-YL 2,3,3-TRICHLOROACRYLATE

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