ChemicalBook Product Catalog Organic Chemistry (3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE

(3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE

(3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE Basic information
Product Name:(3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE
Synonyms:(3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE;(3-Benzyloxypropyl)triphenylphosphonium bromide 98%;(3-Benzyloxypropyl)triphenylphosphonium bromide, 97+% white to off-white powder;triphenyl(3-phenylmethoxypropyl)phosphanium,bromide;3-benzyloxypropyl(triphenyl)phosphonium;triphenyl(3-phenylmethoxypropyl)phosphanium;(3- Benzyloxypropyl}triphenyplhosphoniumbromide
CAS:54314-85-1
MF:C28H28BrOP
MW:491.4
EINECS:
Product Categories:C-C Bond Formation;Olefination;Wittig Reagents
Mol File:54314-85-1.mol
(3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE Structure
(3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE Chemical Properties
Melting point 153-154 °C (lit.)
form Powder
color White to off-white
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2931599090
MSDS Information
ProviderLanguage
SigmaAldrich English
(3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE Usage And Synthesis
Uses(3-Benzyloxypropyl)triphenylphosphonium Bromide is a reagent used in the preparation of antitumor and Her2 degradation activity of geldanamycin and radicicol macrocyclic chimeras.
UsesReactant for preparation of:
  • Spirocyclohexadienones via Pd-catalyzed intramolecular ipso-Friedel-Crafts allylic alkylation
  • Inhibitors of heat shock protein (Hsp90) as antitumor agents
  • Carpanone-like molecules via an oxidative coupling/Diels-Alder cycloaddition sequence
(3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE Preparation Products And Raw materials
Raw materials3-Benzyloxy-1-propanol-->BENZYL 3-BROMOPROPYL ETHER-->Triphenylphosphine
(3-(BENZOYLOXY)PROPYL)TRIPHENYLPHOSPHONIUM BROMIDE (3-BENZYLOXYPROPYL)TRIPHENYLPHOSPHONIUM BROMIDE
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