Vinylferrocene

Vinylferrocene Basic information
Product Name:Vinylferrocene
Synonyms:Ferrocene, ethenyl-;VINYLFERROCENE;Vinylferroceneorangextl;Vinylferrocene,98%;Vinylferrocene ,97%;Vinylferrocene**CUSTOMSYNTHESISPLEASEASK**;Vinylferrocene,99%;Vinylferrocene 97%
CAS:1271-51-8
MF:C12H12Fe10*
MW:212.07
EINECS:215-041-1
Product Categories:metallocene;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis
Mol File:1271-51-8.mol
Vinylferrocene Structure
Vinylferrocene Chemical Properties
Melting point 51-53 °C (lit.)
Boiling point 80-85 °C/0.2 mmHg (lit.)
Fp 144 °F
storage temp. Sealed in dry,2-8°C
form crystal
color orange
Water Solubility Insoluble in water.
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability:Stable. Highly flammable. Incompatible with strong acids, strong oxidizing agents.
NIST Chemistry ReferenceVinylferrocene(1271-51-8)
Safety Information
Hazard Codes F
Risk Statements 11-22
Safety Statements 16-22-24/25-7/9-33
RIDADR UN 1325 4.1/PG 2
WGK Germany 3
10
TSCA No
HazardClass 4.1
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Vinylferrocene Usage And Synthesis
Chemical Propertiescrystalline solid
UsesUsed in the synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides.
DefinitionChEBI: Ferrocene substituted on one of the cyclopentadienyl rings by a vinyl group.
Purification MethodsDissolve vinylferrocene in Et2O, wash it with H2O and brine, dry (Na2SO4), and evaporate to a small volume. Purify it through an Al2O3 (Spence grade H) column by eluting the yellow band with pet ether (b 40-60o). The low melting orange crystals can be sublimed. The tetracyanoethylene adduct crystallises from *C6H6/pentane and has m 137-139o(dec). [Horspool & Sutherland Can J Chem 46 3453 1968, Berger et al. J Org Chem 39 377 1974, Rauch & Siegel J Organomet Chem 11 317 1968, Beilstein 16 III 1787.]
Vinylferrocene Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Lithium Aluminum Hydride-->Acetylferrocene
Preparation ProductsETHYNYLFERROCENE
3-methyl-1-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-1,4-dien-3-ol Methoxyethene inyl-terminated polydimethylsiloxane ETHANE SULFINIC ACID SODIUM SALT Vinyltris(methylethylketoxime)silane Isobutyl vinyl ether Pinacol vinylboronate Sodium ethylenesulphonate NA Ethylenesulfonic acid Vinyl silicone oil TRANS-4-[2-(1-FERROCENYL)VINYL]-1-METHYLPYRIDINIUM IODIDE (1-Cyclohexen-1-yl)ferrocene Aminoferrocene (1-CHLORO-2-FORMYLVINYL)FERROCENE 3-(FERROCENYL)-ACRYLIC ACID CYCLOPENTENYLFERROCENE POLY(VINYLFERROCENE)

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