2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Basic information
Reaction
Product Name:2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL
Synonyms:2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl, min.98%;dicyclohexyl(2',6'-diisopropoxybiphenyl-2-yl)phosphine;{2-[2,6-bis(propan-2-yloxy)phenyl]phenyl}dicyclohexylphosphane;Dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine;2-DicyclohexylphosphiNA-2',6'-diisopropoxy-1,1'-biphenyl;2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl,RuPhos;2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl,98% RuPhos;2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl, 98%
CAS:787618-22-8
MF:C30H43O2P
MW:466.64
EINECS:616-653-5
Product Categories:Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File:787618-22-8.mol
2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Structure
2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Chemical Properties
Melting point 123-124°C
Boiling point 551.7±40.0 °C(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form Powder
color white
Sensitive Air Sensitive
InChIKeyMXFYYFVVIIWKFE-UHFFFAOYSA-N
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36/37/39
WGK Germany 3
TSCA No
HS Code 29310099
MSDS Information
2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Usage And Synthesis
Reaction
  1. Versatile Ligand for the Pd-catalyzed coupling of secondary arylamines and alkylamines.
  2. Ligand used for the Pd-catalyzed Negishi cross-coupling reaction of (hetero)arylchlorides.
  3. Synthesis of ladder-type π-conjugated heteroacenes via palladium-catalyzed double N-arylation and intramolecular O-arylation.
  4. A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles,
  5. Versatile ligand used for the Pd-catalyzed C-N coupling reaction of secondary aryl- and alkyl-amines at low temperature with the Pd precatalyst.
  6. Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.
  7. Ligand for the palladium-catalyzed trifluoromethylation of hindered aryl chlorides.
  8. Ligand used for the palladium-catalyzed coupling of alkyl boronates.
Reactions of 787618-22-8_1
Reactions of 787618-22-8_2
Reactions of 787618-22-8_3
Reactions of 787618-22-8_4


UsesBulky phosphine ligand used in a palladium-catalyzed cross-coupling of aminoethyltrifluoroborate?s with electron-poor aryl bromides.
Uses2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl is the ligand used for the palladium-catalyzed coupling of alkyl boronates.
Usessuzuki reaction
2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Preparation Products And Raw materials
Raw materials1,3-DIISOPROPOXYBENZENE, 97%-->2-BROMO-2',6'-DIISOPROPOXY-1,1'-BIPHENYL-->Dicyclohexylchlorophosphine
Preparation Productst-BuXphos Palladacycle Gen. 4-->RuPhos Pd G3
2-Dicyclohexylphosphino-2',6'-bis(diMethylaMino)-1,1'-biphenyl, Min. 98% Cphos 2-DIPHENYLPHOSPHINO-6-METHYLPYRIDINE 2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl X-PHOS 2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL 2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISO& 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos 2-(Dicyclohexylphosphino)-2'-methoxybiphenyl 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 2'-(Dicyclohexylphosphino)-N,N-dimethyl[1,1'-biphenyl]-4-amine 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl 2-(Dicyclohexylphosphino)-2'-methylbiphenyl DI-N-PENTYLPHENYLPHOSPHINE Dicyclohexylphenylphosphine 2-(DICYCLOHEXYLPHOSPHINO)-2'-HYDROXYBIPHENYL 2-(Dicyclohexylphosphino)biphenyl 2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL

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