4,4'-Dichlorodiphenyl sulfone

4,4'-Dichlorodiphenyl sulfone Basic information

Product Name:	4,4'-Dichlorodiphenyl sulfone
Synonyms:	1,1’-sulfonylbis[4-chloro-benzene];4,4'-Dichlorophenyl sulfone;Benzene, 1,1'-sulfonylbis*4-chloro-;Benzene, 1,1'-sulfonylbis[4-chloro-;di-p-chlorophenylsulfone;p,p’-dichlorodiphenylsulfone;p,p'-Dichlorodiphenyl sulfone;p-Chlorophenyl sulfone
CAS:	80-07-9
MF:	C12H8Cl2O2S
MW:	287.16
EINECS:	201-247-9
Product Categories:	Imidazoles;Organics;Sulphur Derivatives;Diphenyl Sulfones (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;bc0001
Mol File:	80-07-9.mol

4,4'-Dichlorodiphenyl sulfone Chemical Properties

Melting point	143-146 °C(lit.)
Boiling point	250 °C10 mm Hg(lit.)
density	1.54g/cm3
vapor pressure	0Pa at 25℃
Fp	233 °C
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Fine Powder
color	White
Water Solubility	<0.1 g/100 mL at 20 ºC
Sensitive	Moisture Sensitive
BRN	2052955
Stability:	Stable. Combustible. Incompatible with strong oxidizing agents.
LogP	3.9 at 20℃
CAS DataBase Reference	80-07-9(CAS DataBase Reference)
NIST Chemistry Reference	4,4'-Dichlorodiphenyl sulphone(80-07-9)
EPA Substance Registry System	p,p'-Dichlorodiphenyl sulfone (80-07-9)

Safety Information

Hazard Codes	Xi,C
Risk Statements	36/37/38
Safety Statements	22-24/25-37/39-26
WGK Germany	2
RTECS	WR3450000
Hazard Note	Harmful/Corrosive/Moisture Sensitive
TSCA	Yes
HS Code	29309070
Hazardous Substances Data	80-07-9(Hazardous Substances Data)
Toxicity	LD50 orl-mus: 24 g/kg HCACAV 29,1317,46

MSDS Information

Provider	Language
Bis(4-chlorophenyl) sulfone	English
ACROS	English
SigmaAldrich	English
ALFA	English

4,4'-Dichlorodiphenyl sulfone Usage And Synthesis

Chemical Properties	off-white crystals or powder
Uses	4,4’Dichlorodiphenyl Sulfone is an impurity of Dapson (D193250), an antibacterial used in the treatment of dermatitis herpetiformis.
Uses	Bis(4-chlorophenyl) sulfone is used as a precursor to prepare 4,4'-diamino-diphenyl sulfone and polysulfone plastics. It is also used to prepare rigid and temperature resistant polymers such as PES or Udel through polymerization with bisphenol-A and bisphenol-S. Further, the udel polymer finds applications in plumbing pipes, printer cartridges and automobile fuses.
General Description	Crystals or off-white powder.
Air & Water Reactions	Insoluble in water.
Reactivity Profile	4,4'-Dichlorodiphenyl sulfone is incompatible with strong oxidizers.
Fire Hazard	Flash point data for 4,4'-Dichlorodiphenyl sulfone are not available; however, 4,4'-Dichlorodiphenyl sulfone is probably combustible.
Flammability and Explosibility	Nonflammable
Safety Profile	Mildly toxic by ingestion. When heated to decomposition it emitsvery toxic fumes of Cl- and SOx.

4,4'-Dichlorodiphenyl sulfone Preparation Products And Raw materials

Raw materials	Aluminum chloride-->Chlorobenzene
Preparation Products	4-[(4-Chlorophenyl)sulfonyl]benzoic acid-->Bis[4-(4-aminophenoxy)phenyl]sulfone-->Sulfenone-->bis(4-chloro-3-nitrophenyl) sulphone-->4,4'-Diaminodiphenylsulfone

4,4'-Diaminodiphenylsulfone 3-IODO-5-CHLORO-N-[2-CHLORO-5-((4-CHLOROPHENYL)SULPHONYL)PHENYL]-2-HYDROXYBENZAMIDE 3,3',4,4'-TETRACHLORODIPHENYL SULFONE Tetradifon Chloroacetic acid Diphenyl sulfone Ethylbenzene Phenyl sulfoxide Difluorochloromethane 2',4'-Dichloroacetophenone Benzene Chlorobenzene Dichlorodiphenylsilane Epichlorohydrin Allylbenzene Thionyl chloride 4,4'-Dichlorodiphenyl sulfone bis(4-chloro-3-nitrophenyl) sulphone

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