ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic acids Benzyloxyacetic acid

Benzyloxyacetic acid

Benzyloxyacetic acid Basic information
Product Name:Benzyloxyacetic acid
Synonyms:PHENYLMETHOXY ACETIC ACID;RARECHEM AL BE 0628;BENZYLOXYACETIC ACID;ACETIC ACID, (PHENYLMETHOXY)-;benzyloxy acctic acid;Acetic acid, 2-(phenylMethoxy)-;Benzyloxyacetic acid 95%;2-(phenylmethoxy)acetic acid
CAS:30379-55-6
MF:C9H10O3
MW:166.17
EINECS:
Product Categories:Building Blocks/Intermediates;C9;Carbonyl Compounds;Carboxylic Acids
Mol File:30379-55-6.mol
Benzyloxyacetic acid Structure
Benzyloxyacetic acid Chemical Properties
Melting point 80-81 °C
Boiling point 137-139 °C/0.6 mmHg (lit.)
density 1.162 g/mL at 25 °C (lit.)
refractive index n20/D 1.526(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
pka3.52±0.10(Predicted)
form clear liquid
color Colorless to Light orange to Yellow
CAS DataBase Reference30379-55-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HazardClass IRRITANT
HS Code 29189900
MSDS Information
ProviderLanguage
SigmaAldrich English
Benzyloxyacetic acid Usage And Synthesis
Chemical PropertiesColorless liquid
UsesBenzyloxyacetic acid may be used for the following syntheses:
  • mixed benzyloxyacetic pivalic anhydride
  • chiral glycolates, 1,2:4,5-di-O-isopropylidene-β-D-fructopyranos-3-yl benzyloxyacetate, via esterification
  • tetraaqua(1,10-phenanthroline-[κ]2N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate]
  • as ligand in the preparation of diaquabis(benzyloxyacetato)copper(II) complex
UsesIt is a compound for proteomics research use. It may be used for following synthesis mixed benzyloxyacetic pivalic anhydride, chiral glycolates, 1,2:4,5-di-O-isopropylidene-β-D-fructopyranos-3-yl benzyloxyacetate, via esterification, tetra aqua(1,10-phenanthroline-[κ]2N,N?)magnesium(II) bis[(2,4-dichlorophenyl)acetate], as ligand in the preparation of diaquabis(benzyloxyacetato)copper(II) complex.
DefinitionChEBI: (benzyloxy)acetic acid is a monocarboxylic acid that is benzyl alcohol in which the hydroxy group is replaced by a carboxymethoxy group. It is a monocarboxylic acid, an ether and a member of benzenes. It is functionally related to a benzyl alcohol and a glycolic acid.
General DescriptionIn vitro activities of phenoxy and benzyloxyacetic acid derivatives as antisickling agents has been investigated by the application of quantitative structure activity relationship (QSAR) of Hansch-type.
Benzyloxyacetic acid Preparation Products And Raw materials
Preparation Products1-Bromo-4-chlorobutane-->methyl 2-(benzyloxy)acetate-->5-(benzyloxy)-2,4-dichloropyrimidine-->Benzyloxyacetyl chloride
Allyl phenoxyacetate 2-Benzyloxyacetic acid ethyl ester [S,(+)]-α-(Trifluoromethyl)benzyloxyacetic acid BENZOYL LACTIC ACID Ethyl 2-(Chlorosulfonyl)acetate Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate Ascoric Acid [R,(-)]-α-(Trifluoromethyl)benzyloxyacetic acid (+)-DIMETHYL 2,3-O-BENZYLIDENE-D-TARTRATE Dibenzoyltartaric acid DI-P-TOLUOYL-L-TARTARIC ACID (-)-DIMETHYL 2,3-O-BENZYLIDENE-L-TARTRATE ETHYL O-BENZOYLGLYCOLATE Benzyloxyacetic acid benzyl ester phosphoric acid 2,3-Di-O-para-toluoyl-D-tartaric acid (-)-2,3-O-BENZYLIDENE-L-TARTARIC ACID DIETHYL ESTER (2S,3S)-(+)-DIETHYL 2,3-O-BENZYLIDENETARTRATE
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