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| Product Name: | Isobornyl acrylate | | Synonyms: | 1,7,7-trimethylbicyclo(2.2.1)hept-2-ylester,exo-2-propenoicaci;1,7,7-trimethylbicyclo[2.2.1]hept-2-ylester,exo-2-propenoicaci;1,7,7-trimethylbicyclo[2.2.1]hept-2-ylester,exo-2-Propenoicacid;al-co-cureiba;exo-isobornylacrylate;Isobornyl acrylate, stabilized with 100ppm 4-methoxyphenol;sr506(acrylate);ISOBORNYL ACRYLATE | | CAS: | 5888-33-5 | | MF: | C13H20O2 | | MW: | 208.3 | | EINECS: | 227-561-6 | | Product Categories: | | | Mol File: | 5888-33-5.mol |  |
| | Isobornyl acrylate Chemical Properties |
| Melting point | <-35°C | | Boiling point | 119-121 °C15 mm Hg(lit.) | | density | 0.986 g/mL at 25 °C(lit.) | | vapor pressure | 1.3Pa at 20℃ | | refractive index | n20/D 1.476(lit.) | | Fp | 207 °F | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | solubility | Chloroform (Slightly), Methanol (Slightly) | | form | clear liquid | | color | Colorless to Almost colorless | | Water Solubility | Difficult to mix in water. | | Sensitive | Light Sensitive | | BRN | 2254825 | | Stability: | Light sensitive | | InChIKey | PSGCQDPCAWOCSH-BREBYQMCSA-N | | LogP | 4.52 at 20℃ | | CAS DataBase Reference | 5888-33-5(CAS DataBase Reference) | | EPA Substance Registry System | Isobornyl acrylate (5888-33-5) |
| Hazard Codes | Xn,N,Xi | | Risk Statements | 20/22-36/37/38-51/53 | | Safety Statements | 26-36-61-28 | | RIDADR | UN 3082 9 / PGIII | | WGK Germany | 2 | | RTECS | UD3940000 | | TSCA | Yes | | HazardClass | 9 | | PackingGroup | III | | HS Code | 29161290 | | Toxicity | LD50 oral in rat: 4890mg/kg |
| | Isobornyl acrylate Usage And Synthesis |
| Description | Isobornyl acrylate can be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP)1. It is a photo-polymerizable monomer that is employed in micro-fluidic devices because of desirable properties, such as inertness, transparency, and resolution2.
| | Uses | ISOBORNYL ACRYLATE (cas# 5888-33-5) is a useful research chemical. | | Sources |
- https://www.sigmaaldrich.com/catalog/product/aldrich/392103?lang=en®ion=US
- López-García, M. D. C., D. J. Beebe, and W. C. Crone. Characterization of poly(isobornyl acrylate) as a construction material for microfluidic applications. Journal of Applied Polymer Science. 2007:1894–1902.
| | Uses | It is used as UVcuring EBcuring adhesive. | | Uses | Isobornyl acrylate (IBA) can be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP). | | Hazard | Moderately toxic by ingestion. Low toxicity by skin contact. A moderate skin and mild eye
irritant. | | Flammability and Explosibility | Nonflammable | | Synthesis |
Isobornyl acrylate is prepared by reacting (-)- borneol,triethylamine with acryloyl chloride in anhydrous THF.Dissolve (-)- borneol (1.00 g, 6.48 mmol, 1 equiv) and triethylamine (0.98 g, 9.72 mmol, 1.5 equiv) in anhydrous THF (20 mL) in a 100 mL round-bottom flask. Add acryloyl chloride (0.88 g, 9.72 mmol, 1.5 equiv) dropwise to the reaction mixture at 0 °C. Allow the reaction to stir at room temperature overnight. Filter the reaction solution. Concentrate the reaction solution on the rotary evaporator. Wash the mixture with water (20 mL). Extract the mixture with dichloromethane (3x20 mL). Dry the combined organic phases over anhydrous sodium sulfate. Filter and concentrate the residue. Purify the crude product further by silica gel column chromatography (petroleum ether/ethyl acetate = 4:1) to obtain isobornyl acrylate.
Fig Synthetic method of Isobornyl acrylate
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| | Isobornyl acrylate Preparation Products And Raw materials |
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