ChemicalBook Product Catalog Chemical Reagents Organic reagents Phosphine ligand (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Basic information
Reaction
Product Name:(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Synonyms:N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;(R)-SIPHOS;(S)-SIPHOS;(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE;(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE;(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(R)-SIPHOS;N-DIMETHYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (R)-SIPHOS
CAS:443965-14-8
MF:C19H20NO2P
MW:325.34
EINECS:
Product Categories:Chiral Phosphine;Chiral Spiro Ligand;CPN
Mol File:443965-14-8.mol
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Structure
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties
Melting point 95-96°C
alpha +505° (c 0.5, CH2Cl2)
Boiling point 429.6±55.0 °C(Predicted)
pka2.19±0.20(Predicted)
form solid
color white
optical activity[α]22/D +480°, c = 1 in chloroform
Sensitive moisture sensitive
Safety Information
WGK Germany 3
HS Code 29299090
MSDS Information
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Usage And Synthesis
Reaction
  1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
  2. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
  3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
  4. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
  5. Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
  6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
Reactions of 443965-14-8_1
Reactions of 443965-14-8_2
Chemical PropertiesWhite power
Indene (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Dimethylamine
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