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BUTOCARBOXIM

BUTOCARBOXIM Basic information
Product Name:BUTOCARBOXIM
Synonyms:3-METHYLTHIOBUTANONE O-METHYLCARBAMOYLOXIME;(2E)-2-(([(Methylamino)carbonyl]oxy)imino)-3-(methylsulfanyl)butane;2-Butanone, 3-(methylthio)-, O-(N-methylcarbamoyl)oxime;2-Butanone, 3-(methylthio)-, O-[(methylamino)carbonyl]oxime;2-Butanone,3-(methylthio)-,O-(N-methylcarbamoyl)oxime;2-Methylthio-O-(N-methylcarbamoyl)-butanonoxim-3;BUTOCARBOXIM;DRAWIN
CAS:34681-10-2
MF:C7H14N2O2S
MW:190.26
EINECS:252-139-3
Product Categories:A-BPesticides&Metabolites;AcaricidesAlphabetic;Alpha sort;B;BI - BZPesticides;Carbamates;Insecticides;Pesticides;Pesticides&Metabolites
Mol File:34681-10-2.mol
BUTOCARBOXIM Structure
BUTOCARBOXIM Chemical Properties
Melting point 25 °C
density 1.2118 (rough estimate)
vapor pressure 1.1×10-2pa(20°C)
refractive index 1.5690 (estimate)
form neat
Water Solubility 35 g l-1 (20 °C)
pka13.83±0.46(Predicted)
EPA Substance Registry System2-Butanone, 3-(methylthio)-, O-[(methylamino)carbonyl]oxime (34681-10-2)
Safety Information
Hazard Codes T,N
Risk Statements 10-23/24/25-36-50/53
Safety Statements 36/37-45-60-61
RIDADR 2757
WGK Germany 3
RTECS EL9215000
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data34681-10-2(Hazardous Substances Data)
MSDS Information
BUTOCARBOXIM Usage And Synthesis
UsesLabelled Butocarboxim, a systematic selectively acting insecticide with anticholinesterasic activity. Butocarboxim is used to control sucking pests such as mites, aphids, white flies as well as bees i n agriculture.
UsesButocarboxim is a systematic selectively acting insecticide with anticholinesterasic activity. Butocarboxim is used to control sucking pests such as mites, aphids, white flies as well as bees in agric ulture.
Metabolic pathwayButocarboxin is a structural isomer of aldicarb. Butoxycarboxim is the sulfur oxidation (sulfone) product of butocarboxim. Limited information is available to describe the degradation and metabolic fate of these two compounds. As with aldicarb, oxidation of the sulfur molecule of butocarboxim to butocarboxim sulfoxide and butoxycarboxim is the primary photolytic and metabolic reaction in soils, plants and animals (Scheme 1).
DegradationButocarboxim (1) is stable to hydrolytic degradation (pH 5-7, up to 50 °C, PM) and is stable under UV light irradiation. It degrades under strong acidic and alkaline conditions.
Butoxycarboxim (2) is susceptible to alkaline hydrolysis (DT50 values of 500, 18 and 16 days in pH 5, 7 and 9, respectively, PM). It is also stable under UV light irradiation.
BUTOCARBOXIM Preparation Products And Raw materials
Cyhalofop-butyl Bensulfuron methyl Vinyltris(methylethylketoxime)silane Anthraquinone Dibutanone BUTOCARBOXIM SULPHOXIDE,BUTOCARBOXIM SULFOXIDE Methylthio acetaldoxime BUTOXYCARBOXIM 3-(methylthio)butan-2-one oxime Carboxin BUTOCARBOXIM
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