METHYLCYCLOPENTADIENE DIMER

METHYLCYCLOPENTADIENE DIMER Basic information
Product Name:METHYLCYCLOPENTADIENE DIMER
Synonyms:3a,4,7,7a-tetrahydrodimethyl-4,7-methanoindene;3a,4,7,7a-tetrahydrodimethyl-7-methano-1h-indene;3a,4,7,7a-tetrahydrodimethyl-7-methanoindene;4,7-Methano-1H-indene,3a,4,7,7a-tetrahydrodimethyl-;7-Methano-1H-indene,3a,4,7,7a-tetrahydrodimethyl-4;METHYLCYCLOPENTADIENE DIMERS;4,7-Methanoindene, 3a,4,7,7a-tetrahydrodimethyl.;Methylcyclopentadiene dimer 96%
CAS:26472-00-4
MF:C12H16
MW:160.26
EINECS:247-724-5
Product Categories:Norbornene Derivatives;Alkenes;Cyclic;Organic Building Blocks
Mol File:26472-00-4.mol
METHYLCYCLOPENTADIENE DIMER Structure
METHYLCYCLOPENTADIENE DIMER Chemical Properties
Melting point -51 °C (lit.)
Boiling point 200 °C (lit.)
density 0.941 g/mL at 25 °C (lit.)
vapor density 4.6 (vs air)
vapor pressure ~7.5 mm Hg ( 47.8 °C)
refractive index n20/D 1.498(lit.)
Fp 80 °F
storage temp. Flammables area
form Liquid
color Clear colorless to slightly yellow
explosive limit~10%
Water Solubility Insoluble in water.
LogP5.6 at 40℃
CAS DataBase Reference26472-00-4(CAS DataBase Reference)
EPA Substance Registry System4,7-Methano-1H-indene, 3a,4,7,7a-tetrahydrodimethyl- (26472-00-4)
Safety Information
Hazard Codes T,F,N
Risk Statements 45-10-50/53-46
Safety Statements 53-45-61
RIDADR UN 3295 3/PG 3
WGK Germany 3
RTECS PC1075000
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29021990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
METHYLCYCLOPENTADIENE DIMER Usage And Synthesis
Chemical PropertiesClear colorless to slightly yellow liquid
UsesHigh-energy fuels, curing agents, plasticizers,resins, surface coatings, pharmaceuticals, dyes.
UsesMethylcyclopentadiene dimer is used to study the competition with ethylene for binding and biological activities. Used in the synthesis of rubbers and resins intended for use in contact with food or drink.
General DescriptionA colorless liquid. Slightly less dense than water and insoluble in water. Hence floats on water. Flash point 140°F.
Air & Water ReactionsFlammable. Insoluble in water.
Reactivity ProfileMETHYLCYCLOPENTADIENE DIMER may react vigorously with strong oxidizing agents. Can react exothermically with reducing agents to release gaseous hydrogen. May undergo autoxidation upon exposure to the air to form explosive peroxides. Explosions in ammonia synthesis gas have been traced to the breakdown of addition products of dienes similar to this diene and oxides of nitrogen produced from the interaction of nitrogen oxide and oxygen [Bretherick, 1995].
HazardModerate fire risk.
Health HazardHarmful if swallowed, inhaled or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membrane, upper respiratory tract. Exposure can cause nausea, headache, and vomiting. May contain 0.5% Benzene, a known carcinogen.
Fire HazardSpecial Hazards of Combustion Products: Vapors may travel considerable distance to a source of ignition and flash back. Forms explosive mixtures in air. Container explosion may occur under fire conditions.
Flammability and ExplosibilityFlammable
METHYLCYCLOPENTADIENE DIMER Preparation Products And Raw materials
Raw materialsCOAL TAR-->Cracked tar
Preparation ProductsMethyl-5-norbornene-2,3-dicarboxylic anhydride-->1-methylcyclopenta-1,3-diene
Alkenes, C20-24 alpha- 1-OCTADECENE Tungsten hexacarbonyl 3-CYCLOPENTYL-2-METHYL-1-PROPENE 2-METHYLCYCLOPENTADIENE Indene Dicyclopentadiene 1-METHYL-1-CYCLOOCTENE 1-METHYLCYCLOPENTADIENE CYCLOOCTENE 3A,4,7,7A-TETRAHYDROINDENE 4-Vinyl-1-cyclohexene maleic anhydride/ methylcyclopentadiene adduct Norbornene 5-Methylcyclopentadiene Methylcyclopentadienyl manganese tricarbonyl METHYLCYCLOPENTADIENE DIMER DICYCLOPENTADIENE DICARBOXYLIC ACID

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