1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE

1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE Basic information

Product Name:	1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE
Synonyms:	1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE;1,10-DIAZA-18-CROWN-6;KRYPTOFIX 22 POLYMER (SILICA GEL) FOR SYNTHESIS;Diaza-18-crown-6,98%;Diaza-18-crown-6, 98% 500MG;KRYPTOFIX 22 FOR SYNTHESIS;4,13-DIAZA-18-CROWN-6;4,13-DIAZA-18-CROWN 6-ETHER
CAS:	23978-55-4
MF:	C12H26N2O4
MW:	262.35
EINECS:	245-965-0
Product Categories:	Azacrown Ethers;Crown Ethers;Functional Materials;Macrocycles for Host-Guest Chemistry
Mol File:	23978-55-4.mol

1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE Chemical Properties

Melting point	111-114 °C(lit.)
Boiling point	405.6°C (rough estimate)
density	1.0807 (rough estimate)
refractive index	1.4560 (estimate)
storage temp.	Store below +30°C.
pka	9.00±0.20(Predicted)
form	Shiny Crystalline Powder
color	Off-white
Water Solubility	Soluble in water.
BRN	609764
CAS DataBase Reference	23978-55-4(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39-37
WGK Germany	2
RTECS	HM1650000
F	10
HS Code	2934 99 90
Toxicity	LD50 orally in Rabbit: 3400 mg/kg

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE Usage And Synthesis

Chemical Properties	off-white shiny crystalline powder
Uses	1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane is a crown ether, which can be used: In the spectroscopic studies of its complex-forming reaction with iodine. To prepare the ligand 7,16-bis(5-t-butyl-2-hydroxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane. As a ligand in the study of zirconium facilitated hydrolysis of a dipeptide at neutral pH.
Purification Methods	Twice recrystallise it from *benzene/n-heptane, and dry it for 24hours under high vacuum [Weber & V.gtle Top Curr Chem (Springer Verlag, Berlin) 98 1 1981, D'Aprano & Sesta J Phys Chem 91 2415 1987].

1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE Preparation Products And Raw materials

4,7,13,16-Tetraoxa-1,10,26-triazatricyclo[8.8.7.120,24]exacosa-20,22,24(26)-triene-19,25-dione 7,16-bis(4-methoxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane 1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane, 7,16-didecyl- 7,16-BIS[(4-METHYLPHENYL)SULFONYL]-1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE 7,16-(3,6-Dioxaoctane-1,8-diyl)(1,4,10,13-tetraoxa-7,16-diazacyclooctadecane),7,16-[Ethylenebis(oxyethylene)](1,4,10,13-tetraoxa-7,16-diazacyclooctadecane) 7,16-bis{4-nitrobenzyl}-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane 7,16-DIBENZYL-1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE,N,N'-DIBENZYL-1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE 7,16-Bis(carboxymethyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane 7,16-bis[(4-Methylphenyl)sulfonyl]-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane 1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane, 7,16-di(1H-pyrin-6-yl)- 2-Decyl[7,16-(oxybisethylene)(1,4,10,13-tetraoxa-7,16-diazacyclooctadecane)] PBFI-AM 4,4μ-[1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane-7,16-diylbis(5-methoxy-6,2-benzofurandiyl)]bis-1,3-benzenedicarboxylic acid 5,6-BENZO-4,7,13,16,21,24-HEXAOXA-1,10-DIAZABICYCLO[8.8.8]HEXACOS-5-ENE K22B1B5, 7-[(1-Adamantylcarbamoyl)acetyl]-16-[(octadecylcarbamoyl)acetyl]-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane N,N'-BIS(METHOXYMETHYL)DIAZA-18-CROWN-6 7,16-(Ethyleneoxyethylene)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane,7,16-(Oxybisethylene)(1,4,10,13-tetraoxa-7,16-diazacyclooctadecane) 1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE

Email:[email protected] [email protected]

Copyright © 2024 Mywellwork.com All rights reserved.