ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Basic information
Reaction
Product Name:(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Synonyms:(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(11bR)-N,N-Bis[(R)-(-)-1-(2-Methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine, Min. 98%;(11BR)-N,N-BIS[(R)-(-)-1-(2-METHOXYPHENYL)ETHYL]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE,MIN.98%;(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-(2-methoxyphenyl)ethyl]-, (11bR)-;(11bR)-N,N-bis[(1R)-1-(2-methoxyphenyl)ethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS:736158-72-8
MF:C38H34NO4P
MW:599.65
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:736158-72-8.mol
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Structure
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Chemical Properties
Boiling point 760.0±70.0 °C(Predicted)
pka-0.37±0.20(Predicted)
form Powder
color white
Sensitive moisture sensitive
Safety Information
MSDS Information
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Usage And Synthesis
Reaction
  1. Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic and aliphatic substituted allylic halides to form branched chiral products from diverse Grignard and dialkyl zinc reagents.
  2. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from amines, stabilized carbanions, and aryl zinc reagents.
  3. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from alcohol.
  4. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from thiolate.
  5. Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic and aliphatic substituted allylic halides to form branched chiral products from diverse organolithium compounds.
Reactions of 736158-72-8
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Preparation Products And Raw materials
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