4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride

4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride Basic information
Product Name:4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride
Synonyms:4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride;4-(tert-Butyl)-2,6-dimethylphenylsulphur trifluoride;Fluolead, 5-(tert-Butyl)-1,3-dimethyl-1-(trifluorothio)benzene;FLUOLEAD(TM);4-tert-Butyl-2,6-dimethylphenylsulphur trifluoride ,90%;Fluolead, 5-(tert-Butyl)-1,3-dimethyl-2-(trifluorothio)benzene;2,6-Dimethyl-4-tert-butylphenylsulfur trifluoride;Fluolead
CAS:947725-04-4
MF:C12H17F3S
MW:250.32
EINECS:
Product Categories:
Mol File:947725-04-4.mol
4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride Structure
4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride Chemical Properties
Melting point 62-68 °C
Boiling point 92-93℃ (0.5 Torr)
density 1.07±0.1 g/cm3(Predicted)
storage temp. 0-10°C
form crystal
color white to off-white
Safety Information
Hazard Codes T
Risk Statements 14-25-34
Safety Statements 26-36/37/39-45
RIDADR UN 2923 6.1(8) / PGI
WGK Germany 3
TSCA No
HazardClass 8
PackingGroup II
HS Code 29309090
MSDS Information
4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride Usage And Synthesis
Chemical PropertiesWhite powder
UsesAir and thermally stable alternative to DAST. Efficient deoxofluorinating agent for a wide variety of substrates.
UsesFeatures:
  • Tolerance of many functional groups
  • Highly selective functionalization
  • Highly efficient and broad reaction scope
  • Mild reaction conditions

Generally superior reactivity and selectivity to SF4 and easier and safer to handle.

Shown to promote nucleophilic deoxofluorination reactions and exhibits excellent thermal stability, up to 150 °C, therefore rendering it safely applicable in a variety of processes, including industrial scale production.


Novel fluorinating reagent applicable to a variety of chemical processes (Scheme 1).

Refer to the Datasheet for more information on Fluolead?: A Novel New Versatile Fluorinating Agent
Uses4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride is a deoxofluorination reagent used in an improved method of synthesis of arylsulfur trifluorides.
General Description4-tert-Butyl-2,6-dimethylphenylsulfur trifluoride is a thermally stable, easy-to-handle, versatile deoxofluorinating agent that also shows high stability on contact with water. It is a superior alternative to diethylaminosulfur trifluoride (DAST).
4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride Preparation Products And Raw materials
N-Iodosuccinimide

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