(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID

(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Basic information
Product Name:(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID
Synonyms:FMoc-β-azido-Ala-OH;FMOC-L-BETA-AZIDOALANINE;3-Azido-N-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-alanine;Fmoc-L-Dap(N3)-OH;3-Azido-N-Fmoc-L-alanine;Fmoc-L-Aza-OH;2-(S)-Fmoc-amino-3-azidopropanoic acid;Nα-Fmoc-Nβ-Azido-L-2,3-diaminopropionic acidSolvate with DIPE≥ 99% (HPLC)
CAS:684270-46-0
MF:C18H16N4O4
MW:352.35
EINECS:
Product Categories:Fmoc Amino Acids;Fmoc-Amino Acids;amino acids
Mol File:684270-46-0.mol
(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Structure
(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Chemical Properties
Melting point >155 (dec.)
storage temp. 2-8°C
solubility DMF (Slightly), DMSO (Slightly), Methanol (Slightly)
form Solid
color White to Off-White
optical activity[α]/D -10.0±1.0°, c = 1 in DMF
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
HS Code 2924297099
MSDS Information
(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Usage And Synthesis
Chemical PropertiesWhite to off-white crystalline powder
UsesFmoc-β-azido-Ala-OH chloride is a general N-terminal protected reagent used in the solid phase peptide synthesis. Azido group allows it to undergo copper-mediated click chemistry reactions.
It can be used in:
  • Synthesis of α-N-acetylgalactosamine (α-GalNAc) linked antifreeze glycopeptides (AFGPs).
  • Synthesis of stimuli-responsive multifunctional peptide gatekeepers for drug delivery applications.
  • Synthesis of triazole-linked glycopeptides via Cu(I)-catalyzed 1,3-dipolar cycloaddition (CuAAC).

(S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID Preparation Products And Raw materials
Raw materialsFmoc-L-Dapa-OH
FMOC-Ala-OH FMOC-D-DAB(MTT)-OH FMOC-D-DAP(MTT)-OH (S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-4-AZIDOBUTANOIC ACID FMOC-L-Arginine FMOC-D-DAP(Z)-OH L-Lysine, N6-[[[(2,3-dihydro-2,2,4,6,7-pentamethyl-5-benzofuranyl)sulfonyl]amino]iminomethyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]- FMOC-D-alanine Fmoc-D-Arg(Pbf)-OH (S,E)-12-(9H-fluoren-9-yl)-3-(methylamino)-10-oxo-11-oxa-2,4,9-triazadodec-2-ene-8-carboxylic acid Fmoc-D-homoArg(Boc)2-OH FMOC-ARG(ME,PBF)-OH FMOC-Arg(Pbf)-OH Fmoc-HomoArg(Boc)2-OH N-Fmoc-N'-(4-methoxy-2,3,6-trimethylbenzenesulfonyl)-L-arginine FMOC-ALA-OPFP FMOC-b-Ala-OH (S)-2-(((9H-FLUOREN-9-YL)METHOXY)CARBONYLAMINO)-3-AZIDOPROPANOIC ACID

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