2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE

2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE Basic information
Product Name:2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE
Synonyms:2,4-dimethyl-3-cyclohexene-1-carboxaldehyd;Ligustral,triplal;Vergustral;2,6-dimethylcyclohex-2-enecarbaldehyde;2,4-Dimethyl-3-Cyclohexenecarboxaldehyde (mixture of isomers);2 4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYD&;3-Cyclohexene-1-carboxaldehyde, 2,4-dimethyl- (9CI);LIGUSTRAL
CAS:68039-49-6
MF:C9H14O
MW:138.21
EINECS:268-264-1
Product Categories:Alphabetical Listings;C-D;ALDEHYDE;Aroma Chemicals;Flavors and Fragrances
Mol File:68039-49-6.mol
2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE Structure
2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE Chemical Properties
Melting point 85-90 °C
Boiling point 196 °C(lit.)
density 0.933 g/mL at 25 °C(lit.)
refractive index n20/D 1.473(lit.)
Fp 151 °F
form clear liquid
color Colorless to Almost colorless
Odorat 10.00 % in dipropylene glycol. green aldehydic leafy cortex tart floral peely
Odor Typegreen
LogP2.67
EPA Substance Registry System3-Cyclohexene-1-carboxaldehyde, 2,4-dimethyl- (68039-49-6)
Safety Information
RIDADR NA 1993 / PGIII
WGK Germany 2
HS Code 2912.29.6090
MSDS Information
2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE Usage And Synthesis
Chemical Properties2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE is prepared as a mixture of its cis- and trans-isomers by a Diels–Alder reaction of 2-methyl-1,3-pentadiene and acrolein. It is a liquid with a strongly green, slightly herbaceous, citrus note. It is used for perfuming cosmetic preparations as well as household products.
Uses2,4-Dimethyl-3-cyclohexenecarboxaldehyde is used in method for improving performance of fragrance or its mixture.
Trade nameCyclal C (Givaudan), Lantral (Hangzhou), Triplal® (IFF), Vertocitral (Symrise).
2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE Preparation Products And Raw materials
Raw materialsAcrolein-->Diacetone Alcohol-->TRANS-2-METHYL-1,3-PENTADIENE
spirocardin B penasterol 2-METHYL-4-OXO-6-PENTYL-CYCLOHEX-2-ENECARBOXYLIC ACID METHYL ESTER Muzigadial spirocardin A (E)-1-(2,6,6-TRIMETHYL-CYCLOHEX-2-ENYL)-BUT-2-EN-1-ONE 6-ISOPROPYL-2-METHYL-4-OXO-CYCLOHEX-2-ENECARBOXYLIC ACID METHYL ESTER Fenaftic RUGULOSIN UCT 4B POLYGODIAL GIVESCONE CALYXOL 5-(2,5-DIOXOTETRAHYDROFURYL)-3-METHYL-3-CYCLOHEXENE-1,2-DICARBOXYLIC ANHYDRIDE RUBROSKYRIN 2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE CINNAMODIAL 6-HEPTYL-2-METHYL-4-OXO-CYCLOHEX-2-ENECARBOXYLIC ACID ETHYL ESTER

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