Ethylene glycol diethyl ether

Ethylene glycol diethyl ether Basic information
Product Name:Ethylene glycol diethyl ether
Synonyms:1,2-ethanediol,diethylether;2-Ethoxyethyl ethyl ether;2-ethoxyethylethylether;3,6-Dioxaoctane;Diethylether ethylenglykolu;diethyletherethylenglykolu;Ethane,1,2-diethoxy-;Ethyl glyme
CAS:629-14-1
MF:C6H14O2
MW:118.17
EINECS:211-076-1
Product Categories:Amber Glass Bottles;Essential Chemicals;Inorganic Salts;Reagent;Research Essentials;Solutions and Reagents;Solvent Bottles;Solvent Packaging Options;Solvents;Technical Grade;Synthetic Flavours & Fragrances
Mol File:629-14-1.mol
Ethylene glycol diethyl ether Structure
Ethylene glycol diethyl ether Chemical Properties
Melting point -74 °C
Boiling point 121 °C(lit.)
density 0.842 g/mL at 25 °C(lit.)
vapor pressure 9.4 mm Hg ( 20 °C)
refractive index n20/D 1.3923(lit.)
Fp 69 °F
storage temp. Store below +30°C.
solubility 34g/l
form Liquid
color Clear colorless
Water Solubility Slightly soluble
BRN 1732917
CAS DataBase Reference629-14-1(CAS DataBase Reference)
NIST Chemistry ReferenceEthane, 1,2-diethoxy-(629-14-1)
EPA Substance Registry SystemEthylene glycol diethyl ether (629-14-1)
Safety Information
Hazard Codes Xi,T,F
Risk Statements 10-37/38-41-62-36-19-11-61-60
Safety Statements 16-26-36-45-53
RIDADR UN 1153 3/PG 2
WGK Germany 2
RTECS KI1225000
Autoignition Temperature208 °C
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29091900
Hazardous Substances Data629-14-1(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 2350 mg/kg
MSDS Information
ProviderLanguage
1,2-Diethoxyethane English
SigmaAldrich English
ALFA English
Ethylene glycol diethyl ether Usage And Synthesis
Chemical PropertiesClear colorless liquid
Chemical PropertiesEthylene glycol diethyl ether is a colorless liquid.
UsesEthylene glycol diethyl ether is a important solvent, used for ink, paint and coating industry. Mainly used in polymer, electrochemistry, boracium chemistry, resin, nitro cellulose, In this product , the benzene, xenene, terphenyl, anthracene reacts with sodium and then bring about the complex; it is also used in surface treatment, halogen analysis in gasoline, acetic acid recycle in diluted acetic acid, depaint agent, thinner, flushing agent, stabilizer, anti oxidant , thickener of lube.
General DescriptionA clear colorless liquid with a faint ether-like odor. Flash point 95°F. Less dense than water and insoluble in water. Vapors heavier than air.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileEthylene glycol diethyl ether can react with oxidizers. Ethylene glycol diethyl ether is incompatible with strong acids.
Health HazardInhalation causes irritation of nose and throat. Contact with liquid irritates eyes but has little or no effect on skin. Ingestion causes irritation of mouth and stomach.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety ProfileModerately toxic by ingestion. Mildly toxic by inhalation. An experimental teratogen. Experimental reproductive effects. An eye irritant. An aprotic solvent. A very dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. To fight fire, use CO2, dry chemical. See also GLYCOL ETHERS and various cellosolve entries.
Potential ExposureEthylene glycol diethyl ether is used as an aprotic solvent; in chemical manufacturing; as a solvent for detergents and in other cleaning products
ShippingUN1153 Ethylene glycol diethyl ether, Hazard Class: 3; Labels: 3-Flammable liquid
Purification MethodsAfter refluxing for 12hours, a mixture of the ether (2L), conc HCl (27mL) and water (200mL), is added with slow passage of nitrogen. The solution is cooled, and KOH pellets are added slowly and with shaking until no more dissolves. The organic layer is decanted, treated with some KOH pellets and again decanted. It is then refluxed with, and distilled from sodium immediately before use. Alternatively, after removal of peroxides by treatment with activated alumina, the ether is refluxed in the presence of the blue ketyl formed by sodium-potassium alloy with benzophenone, then distilled. [Beilstein 1 H 468, 1 II 519, 1 III 2078, 1 IV 2379.]
IncompatibilitiesForms explosive mixture with air when heated. Incompatible with oxidizers (chlorates, nitrates,peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Attacks some plastics, rubber and coatings. May slowly form unstable reactive peroxides during prolonged storage or on exposure to air and light. Also incompatible with strong acids; aluminum and its alloys
Ethylene glycol diethyl ether Preparation Products And Raw materials
ETHYLENE GLYCOL MONO-TERT-BUTYL ETHER Ethylene glycol diphenyl ether 2-[2-(2-CHLOROETHOXY)ETHOXY]ETHANOL 1,6-ANHYDRO-3,4-O-ISOPROPYLIDENE-2-TOSYL-B-D-GALACTOPYRANOSE Triethylene glycol DIGOXIN Ethylene glycol diethyl ether HEXA(2-CYANOETHOXY) CYCLOHEXANE 1,2:3,5-Di-O-isopropylidene-alpha-D-xylofuranose Dibenzoyltartaric acid 2-(2-ETHOXYETHOXY)ETHAN(OL-D) PENTAETHYLENE GLYCOL Glycol dimercaptoacetate 1,2-Bis(2-chloroethoxy)ethane Bis[2-(2-hydroxyethoxy)ethyl] ether Ethylenebis(oxyethylenenitrilo)tetraacetic acid HEPTAETHYLENE GLYCOL Hexaethylene glycol

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