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| | Tetramethylene sulfoxide Basic information |
| Product Name: | Tetramethylene sulfoxide | | Synonyms: | TetraMethylene sulfoxide, 98+% 5GR;Tetrahydrothiophene 1-oxide 96%;TETRAMETHYLENE SULFOXIDE;TETRAMETHYLENE SULPHOXIDE;tetrahydro-thiophen1-oxide;Tetrametylene sulfoxide;Thiolane 1-oxide;Thiophane 1-oxide | | CAS: | 1600-44-8 | | MF: | C4H8OS | | MW: | 104.17 | | EINECS: | 216-493-2 | | Product Categories: | | | Mol File: | 1600-44-8.mol |  |
| | Tetramethylene sulfoxide Chemical Properties |
| Safety Statements | 24/25 | | WGK Germany | 3 | | RTECS | XN0830000 | | TSCA | T | | HS Code | 29041000 | | Toxicity | mouse,LD50,intraperitoneal,3500mg/kg (3500mg/kg),International Journal of Radiation Biology and Related Studies in Physics, Chemistry and Medicine. Vol. 3, Pg. 41, 1961. |
| | Tetramethylene sulfoxide Usage And Synthesis |
| Chemical Properties | clear colorless to yellow liquid | | Uses | In a comparative study of aromatic fluorodenitration with Potassium fluoride, in several dipolar aprotic solvents, a much faster reaction rate was observed with DMSO or tetramethylene sulfoxide than with the more commonly used Sulfolane. | | Definition | ChEBI: Tetrahydrothiophene 1-oxide is a member of tetrahydrothiophenes. | | Synthesis Reference(s) | Journal of the American Chemical Society, 63, p. 2939, 1941 DOI: 10.1021/ja01856a021
The Journal of Organic Chemistry, 50, p. 1787, 1985 DOI: 10.1021/jo00210a055
Synthetic Communications, 24, p. 2393, 1994 DOI: 10.1080/00397919408010545 | | Purification Methods | Shake the oxide with BaO for 4 days, then distil it from CaH2 under reduced pressure. [Beilstein 17 III/IV 36, 17/1 V 38.] |
| | Tetramethylene sulfoxide Preparation Products And Raw materials |
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