2,2-DIPHENYL-1-PICRYLHYDRAZYL

2,2-DIPHENYL-1-PICRYLHYDRAZYL Basic information
Product Name:2,2-DIPHENYL-1-PICRYLHYDRAZYL
Synonyms:2,2-Diphenyl-1-picrylhydrazyl,1,1-Diphenyl-2-picrylhydrazyl radical, 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl, DPPH;1-diphenyl-2-picrylhydrazyl;1,1-Diphenyl-2-picrylhydrazyl (DPPH);2,2-Diphenyl-1-(2,4,6-trinitrophenyl)-hydrazyl (DPPH);1,1-Diphenyl-2-picrylhydrazyl radical, 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl, DPPH;1,1-Diphenyl-2-picrylhydrazyl Free Radical (contains 10-20% Benzene);[1-(2,4,6-Trinitrophenyl)-2,2-diphenylhydrazino]radical;2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazino radical
CAS:1898-66-4
MF:C18H12N5O6*
MW:394.32
EINECS:217-591-8
Product Categories:Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes;DPPH
Mol File:1898-66-4.mol
2,2-DIPHENYL-1-PICRYLHYDRAZYL Structure
2,2-DIPHENYL-1-PICRYLHYDRAZYL Chemical Properties
Melting point ~135 °C (dec.)(lit.)
density 1.484 g/cm3
storage temp. 2-8°C
solubility Acetonitrile (Slightly), Chloroform (Slightly), DMSO (Slightly)
form Solid
color green
Water Solubility Soluble in dimethyl formamide, ethanol, chloroform, ether, carbon disulfinde, acetone, oils, carbon tetrachloride, glacial acetic acid and toluene. Insoluble in water.
λmax515nm(MeOH)(lit.)
Merck 14,3330
BRN 1846081
Stability:Shock Sensitive
EPA Substance Registry SystemHydrazyl, 2,2-diphenyl-1-(2,4,6-trinitrophenyl)- (1898-66-4)
Safety Information
Hazard Codes Xn
Risk Statements 42/43
Safety Statements 22-36/37-45
RIDADR UN2811
WGK Germany 1
RTECS MW3250000
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29280000
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2,2-DIPHENYL-1-PICRYLHYDRAZYL Usage And Synthesis
Chemical PropertiesSolid
Uses2,2-Diphenyl-1-picrylhydrazyl is used as a sensitive colorimetric free radical scavenger. It serves as a general antioxidant detector. It is utilized to monitor chemical reactions involving radicals as well as a standard of the position and intensity of electron paramagnetic resonance signals. Further, it is employed in the quantitative determination of aliphatic and aromatic thiols by indirect spectroscopy and for photometric determination of tocopherol.
Uses2,2-Diphenyl-1-picrylhydrazyl is a stable free radical molecule most commonly used as a tool to monitor chemical reactions involving radicals, most notably in antioxidant assay.
General Description2,2-diphenyl-1-picrylhydrazyl is a free radical, which shows hydrogen acceptor ability towards antioxidants. Hence, it is commonly used in DPPH assay for measuring the antioxidant activity of different natural samples such as wine, fruits, herbal tea etc.
1,4-Diamino-2-nitrobenzene 2,6-Dinitroaniline 2,4-Dinitroaniline 1,1-Diphenyl-2-picrylhydrazyl,free radical 3,5-DIAMINONITROBENZENE 1,2,3-TRIAMINOBENZENE 1,1-DIPHENYLHYDRAZINE 1,1Diphenyl-2-Picrylhydrazyl,>85% 3,5-DINITROANILINE 2,2-DI(4-TERT-OCTYLPHENYL)-1-PICRYL-HYDRAZYL, FREE RADICAL 2-Nitrophenylhydrazine 4-Nitrophenylhydrazine 1,3,5-TRIAMINOBENZENE 1,2-Diamino-3-nitrobenzene 1,1-DIPHENYL-2-PICRYLHYDRAZINE 1,3,5-TRINITROBENZENE 2,2-DIPHENYL-1-PICRYLHYDRAZYL 2,4,6-TRINITROANILINE

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