4-METHOXY-3-METHYLPHENYLBORONIC ACID

4-METHOXY-3-METHYLPHENYLBORONIC ACID Basic information
Product Name:4-METHOXY-3-METHYLPHENYLBORONIC ACID
Synonyms:AKOS BRN-0220;4-METHOXY-3-METHYLBENZENEBORONIC ACID;4-METHOXY-3-METHYLPHENYLBORONIC ACID;TIMTEC-BB SBB005903;4-Methoxy-3-methylbenzeneboronic acid 98%;m122;4-METHOXY-3-METHYLBENZENEBORONIC ACID, 98+%;1-Methoxy-2-Methylphenylboronic acid
CAS:175883-62-2
MF:C8H11BO3
MW:165.98
EINECS:
Product Categories:Aryl;Boronic Acids;blocks;BoronicAcids;Boronic Acids and Derivatives;Organoborons
Mol File:175883-62-2.mol
4-METHOXY-3-METHYLPHENYLBORONIC ACID Structure
4-METHOXY-3-METHYLPHENYLBORONIC ACID Chemical Properties
Melting point 205-210 °C (lit.)
Boiling point 321.4±52.0 °C(Predicted)
density 1.14±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka9.00±0.10(Predicted)
form Powder
color White to pale purple
BRN 7475212
CAS DataBase Reference175883-62-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
HazardClass IRRITANT
HS Code 2931900090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
4-METHOXY-3-METHYLPHENYLBORONIC ACID Usage And Synthesis
Usessuzuki reaction
UsesReactant for:
  • Preparation of hydroxyphenylnaphthols as 17β-hydroxysteroid dehydrogenase Type 2 inhibitors
  • Synthesis of bioactive combretastatin analogs via regioselective Suzuki coupling
  • Preparation of aromatic nitriles via copper-mediated cyanation
  • Rhodium-catalyzed allylic arylation of meso cyclopentene dicarbonates
  • Lewis acid-assisted asymmetric allylic substitution of butenediyl carbonates using rhodium catalyst
4-METHOXY-3-METHYLPHENYLBORONIC ACID Preparation Products And Raw materials
Raw materials4-METHOXY-3-METHYLPHENYLMAGNESIUM BROMIDE-->4-BROMO-2-METHYLANISOLE-->Triisopropyl borate
Preparation Products3-(4-Methoxy-3-methylphenyl)prop-1-ene
4-BENZYLOXY-3-CHLORO-5-METHYLPHENYLBORONIC ACID CHROMONE-6-BORONIC ACID PINACOL ESTER 4-(3'-CHLOROBENZYLOXY)-3,5-DIMETHYLPHEN& 4-BENZYLOXY-3-FORMYLPHENYLBORONIC ACID 3,5-DIMETHYL-4-ETHOXYPHENYLBORONIC ACID 4-(4'-CHLOROBENZYLOXY)-3,5-DIMETHYLPHEN& 4-ISOPROPOXY-3-METHYLPHENYLBORONIC ACID 2,3-DIHYDROBENZOFURAN-5-BORONIC ACID 3-CARBOXY-4-METHOXYPHENYLBORONIC ACID 4-Benzyloxy-3-methylbenzeneboronic acid 3-CHLORO-4-METHOXY-5-METHYLPHENYLBORONIC ACID 4-Benzyloxy-3,5-dimethylphenylboronic acid 4-ETHOXY-3-METHYLPHENYLBORONIC ACID 3,5-DIMETHYL-4-PROPOXYPHENYLBORONIC ACID 5-METHYL-4-PROPOXY-1,3-PHENYLENEBISBORONIC ACID 4-METHOXY-3-METHYLPHENYLBORONIC ACID 4-(2'-CHLOROBENZYLOXY)-3,5-DIMETHYLPHEN& 2-BUTOXY-3,5-DIMETHYLPHENYLBORONIC ACID

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