(ACETYLACETONATO)DICARBONYLIRIDIUM(I)

(ACETYLACETONATO)DICARBONYLIRIDIUM(I) Basic information
Product Name:(ACETYLACETONATO)DICARBONYLIRIDIUM(I)
Synonyms:DICARBONYL-2,4-PENTANEDIONATOIRIDATE (I);DICARBONYLACETYLACETONATO IRIDIUM (I);IRIDIUM I DICARBONYL PENTANEDIONATE;(ACETYLACETONATO)DICARBONYLIRIDIUM(I);dicarbonyl(2,4-pentandione)iridium;Iridium, dicarbonyl(2,4-pentanedionato-O,O')-;DicarbonylacetylacetonatoiridiumIcopperbrownxtl;dicarbonyl-2,4-pentanedionatoiridium(i)
CAS:14023-80-4
MF:C7H7IrO4
MW:347.35
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Iridium;metal carbonyl complexes
Mol File:14023-80-4.mol
(ACETYLACETONATO)DICARBONYLIRIDIUM(I) Structure
(ACETYLACETONATO)DICARBONYLIRIDIUM(I) Chemical Properties
Melting point >145℃
Boiling point 100°C 0,05mm
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color copper brown
Stability:store cold
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38-63
Safety Statements 22-26-36
RIDADR UN3466
WGK Germany 3
TSCA No
HazardClass 6.1
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
(ACETYLACETONATO)DICARBONYLIRIDIUM(I) Usage And Synthesis
Chemical Propertiesmetallic brown
UsesCatalyst for isomerization and anti-Markovnikov arylation of olefins

Reactant for:
  • Oxidative addition of perfluoroalkyl iodides
  • Synthesis of iridium heterocycles
  • Scaffolding of iridium complexes
  • Metal carbonyl cluster synthesis
  • Mixed-bridged bimetallic d8 complex synthesis
(ACETYLACETONATO)DICARBONYLIRIDIUM(I) Preparation Products And Raw materials
Dipotassium hexachloroiridate Ruthenium tetroxide Tris(triphenylphosphine)rhodiu Rhodium triiodide Hydridotetrakis(triphenylphosphine)rhodium(I) Carbonyltris(triphenylphosphine)rhodium(I) hydride Chloroiridic acid Tris(triphenylphosphine)ruthenium(II) chloride Iridium(IV) chloride Ruthenium dioxide Rhodium(II) octanoate dimer Rhodium(III) Chloride Iridium(III) chloride hydrate Rhodium(III) sulfate Ruthenium(III) chloride hydrate(1:x) (ACETYLACETONATO)DICARBONYLIRIDIUM(I) Iridium DODECACARBONYLTETRAIRIDIUM

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