(+)-N-METHYLEPHEDRINE

(+)-N-METHYLEPHEDRINE Basic information
Product Name:(+)-N-METHYLEPHEDRINE
Synonyms:(+)-N-METHYLEPHEDRINE;(+)-(1S,2R)-2-DIMETHYLAMINO-1-PHENYLPROPANOL;(1S,2R)-(+)-N-METHYLEPHEDRINE;Benzenemethanol, α-[(1R)-1-(dimethylamino)ethyl]-, (αS)-;Benzenemethanol, α-[1-(dimethylamino)ethyl]-, [S-(R*,S*)]-;d-N-Methylephedrine;L-(+)-erythro-N-Methylephedrine;(+)-N-METHYLEPHEDRINE 98%
CAS:42151-56-4
MF:C11H17NO
MW:179.26
EINECS:
Product Categories:
Mol File:42151-56-4.mol
(+)-N-METHYLEPHEDRINE Structure
(+)-N-METHYLEPHEDRINE Chemical Properties
Melting point 87-90 °C(lit.)
Boiling point 311.8°C (rough estimate)
density 1.0020 (rough estimate)
refractive index 1.5320 (estimate)
storage temp. 2-8°C
pka13.88±0.20(Predicted)
optical activity[α]20/D +29°, c = 5 in methanol
BRN 3198945
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
(+)-N-METHYLEPHEDRINE Usage And Synthesis
Chemical PropertiesWHITE CRYSTALLINE POWDER
Purification MethodsN-Methylephedrine has been recrystallised from Et2O, pet ether, of aqueous EtOH or aqueous MeOH and has been distilled under reduced pressure. [Smith J Chem Soc 2056 1927, Tanaka & Sugawa Yakugaku Zasshi (J Pharm Soc Japan) 72 1548 1952 (Chem Abstr 47 8682 1953), Takamatsu Yakugaku Zasshi (J Pharm Soc Japan) 76 1227 1956, Chem Abstr 51 4304 1957.] The hydrochloride has m 192-193o and [] D (c 5,H2O)[Prelog & Hüfliger Helv Chim Acta 33 2021 1950].20+30o [Beilstein 13 IV 1884.]
(+)-N-METHYLEPHEDRINE Preparation Products And Raw materials
N-CROTONYL-(4R,5S)-4-METHYL 5-PHENYL-2-OXAZOLIDINONE tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate N-PROPIONYL-(4S,5R)-4-METHYL- 5-PHENYL-2-OXAZOLIDINONE Sunagrel (-)-BETA-HYDRASTINE N-ACETYL-(4S,5R)-4-METHYL 5-PHENYL-2-OXAZOLIDINONE AKOS 244-30 (-)-ALPHA-[1-(DIBUTYLAMINO)ETHYL]BENZYL ALCOHOL NOSCAPINE HYDROCHLORIDE TIMTEC-BB SBB006457 (-)-BICUCULLINE METHOCHLORIDE gypsetin 458L Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate (-)-YENHUSOMIDINE (+)-N-METHYLEPHEDRINE (R)-alpha,alpha-Diphenylmethylprolinol NOSCAPINE HYDROCHLORIDE HYDRATE

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