4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL

4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Basic information
Product Name:4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
Synonyms:RARECHEM AL BO 1387;4-CARBOXY-TEMPO;4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL;4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINYLOXY;4-CARBOXY-TEMPO, FREE RADICAL, 97%;4-Carboxy-2,2,6,6-tetramethylpiperidine1-oxylfreeradical[spinlabel];4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL, FREE RADICAL;4-carboxy-2,2,6,6-tetramethylpiperidinyloxy, free radical
CAS:37149-18-1
MF:C10H18NO3*
MW:200.25
EINECS:
Product Categories:Analytical Chemistry;ESR Spectrometry;Spin Labels
Mol File:37149-18-1.mol
4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Structure
4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Chemical Properties
Melting point 185-189 °C(lit.)
storage temp. 2-8°C
solubility DMF: 30 mg/ml; DMSO: 30 mg/ml; Ethanol: 30 mg/ml; PBS (pH 7.2): 10 mg/ml
form powder to crystal
color Light yellow to Brown
BRN 3949026
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2933.39.9200
MSDS Information
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SigmaAldrich English
4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Usage And Synthesis
Uses4-Carboxy-TEMPO may be employed as catalyst for the oxidation of regenerated cellulose (viscose rayon) to cellouronic acid. 4-Carboxy-TEMPO is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative. 4-carboxy-TEMPO immobilized with 3-aminopropylsilane on the mesoporous silica surface comprises heterogeneous catalytic system employed for various oxidation reactions.
DefinitionChEBI: 4-carboxy-TEMPO is a member of the class of aminoxyls that is TEMPO carrying a carboxy group at position 4. It has a role as a radical scavenger, a MRI contrast agent and a spin label. It is a member of aminoxyls and a piperidinemonocarboxylic acid. It is functionally related to a TEMPO.
General Description4-Carboxy-TEMPO is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative. 4-carboxy-TEMPO immobilized with 3-aminopropylsilane on the mesoporous silica surface comprises heterogeneous catalytic system employed for various oxidation reactions.
4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Preparation Products And Raw materials
4-Amino-TEMPO, free radical N-(TERT-BUTYL)HYDROXYLAMINE ACETATE 97 FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID 2,2,6,6-Tetramethylpiperidine 2,4-Dimethylpiperidine 4-amino-4-carboxy-2,2,6,6-tetramethylpiperidine-1-oxyl 2,2,6,6-Tetramethylpiperidinooxy 4-CARBOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL

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