1-Bromo-3-phenylpropane

1-Bromo-3-phenylpropane Basic information

Product Name:	1-Bromo-3-phenylpropane
Synonyms:	TIMTEC-BB SBB008835;3-PHENYLPROPYL BROMIDE;(3-BROMOPROPYL)BENZENE;3-BROMO-1-PHENYLPROPANE;gamma-Phenylpropyl bromide;1-BROMO-3-PHENYLPROPANE;G-PHENYLPROPYL BROMIDE;Hydrocinnamyl bromide
CAS:	637-59-2
MF:	C9H11Br
MW:	199.09
EINECS:	211-294-7
Product Categories:	Bromine Compounds
Mol File:	637-59-2.mol

1-Bromo-3-phenylpropane Chemical Properties

Melting point	-10°C (estimate)
Boiling point	237-238 °C (lit.)
density	1.31 g/mL at 25 °C (lit.)
refractive index	n20/D 1.546(lit.)
Fp	215 °F
storage temp.	Inert atmosphere,Room Temperature
solubility	Chloroform, Methanol
form	Liquid
color	Clear colorless to light yellow
Specific Gravity	1.31
Water Solubility	INSOLUBLE
BRN	2205527
CAS DataBase Reference	637-59-2(CAS DataBase Reference)
NIST Chemistry Reference	1-Bromo-3-phenylpropane(637-59-2)
EPA Substance Registry System	(3-Bromopropyl)benzene (637-59-2)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	22-36/38-36/37/38
Safety Statements	26-37/39
RIDADR	2810
WGK Germany	3
TSCA	Yes
HS Code	29036990

MSDS Information

Provider	Language
1-Bromo-3-phenylpropane	English
ACROS	English
SigmaAldrich	English
ALFA	English

1-Bromo-3-phenylpropane Usage And Synthesis

Chemical Properties	Colorless to light yellow liqui
Uses	1-Bromo-3-phenylpropane is used in the synthesis of MraY natural inhibitors as antibacterial agents. Also used in the preparation of quinolinone derivatives as potent and selective MAO-B inhibitors.
Synthesis Reference(s)	Chemical and Pharmaceutical Bulletin, 31, p. 4189, 1983 DOI: 10.1248/cpb.31.4189
Purification Methods	Wash the bromide successively with conc H2SO4, water, 10% aqueous Na2CO3 and again with water, then dry it with CaCl2 and fractionally distil it just before use. [Beilstein 5 IV 982.]

1-Bromo-3-phenylpropane Preparation Products And Raw materials

Raw materials	Benzenepropanol, 1-methanesulfonate-->3-Phenylpropyl 4-methylbenzenesulfonate
Preparation Products	5-PHENYL-1-PENTYNE-->1-BROMO-8-PHENYLOCTANE-->8-PHENYL-1-OCTANOL-->3-PHENYLPROPYL TRIPHENYLPHOSPHONIUM BROMIDE-->N-(4-Methyl-2-nitrophenyl)benzenepropanaMine-->Thiosulfuric acid hydrogen S-[2-[(3-phenylpropyl)amino]ethyl] ester-->Benzenemethanol, 3-methoxy-4-(3-phenylpropoxy)-

N-PROPYLBENZENE 1-BROMO-2-PHENYLPROPANE 1,3-Propane sultone 2-Bromopropane Rocuronium bromide 3-BROMO-1-PHENYLPROPANE-1,2-DIONE Sodium bromate Benzene 1-Phenyl-2-nitropropene Ethidium bromide Bromine Allyl bromide 1-Bromopropane 2-BROMO-1-PHENYLPROPANE,2-BROMO-1-PHENYLPROPANE 98% 1-Bromo-3-phenylpropane Propiophenone 1-CHLORO-2-BROMO-3-PHENYLPROPANE Methyl bromide

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