TPP

TPP Basic information
Product Name:TPP
Synonyms:meso-Tetraphenylporphyrine;Porphine, 5,10,15,20-tetraphenyl-;RARECHEM AS SA 0001;TETRAPHENYLPORPHINE METAL FREE;TETRAPHENYLPORFYRIN;5,10,15,20-TETRAPHENYL-21H,23H-PORPHYRIN;ALPHA,BETA,GAMMA,EPSILON-TETRAPHENYLPORPHIN;A B G D-TETRAPHENYLPORPHINE
CAS:917-23-7
MF:C44H30N4
MW:614.74
EINECS:213-025-9
Product Categories:electronic;Porphyrins;Synthetic Porphyrins;Ligands for Pharmaceutical Research;Magnetic Resonance Imaging (Chelating Reagents);Imidazoles ,Heterocyclic Acids;porphine (porphyrin) ligand;Analytical Chemistry;Biochemistry;Chelating Reagents;Porphines;Environmentally-friendly Oxidation;Ligands (Environmentally-friendly Oxidation);Synthetic Organic Chemistry;Organics
Mol File:917-23-7.mol
TPP Structure
TPP Chemical Properties
Melting point 300 °C
Boiling point 648.45°C (rough estimate)
density 1.5288 (rough estimate)
refractive index 1.7030 (estimate)
storage temp. Inert atmosphere,Room Temperature
solubility dichloromethane: soluble
form Glistening Crystalline Powder
color Blue to purple
Water Solubility Insoluble in water.
BRN 379542
Stability:Light Sensitive
InChIKeyYNHJECZULSZAQK-LWQDQPMZSA-N
EPA Substance Registry System21H,23H-Porphine, 5,10,15,20-tetraphenyl- (917-23-7)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
8-10-23
TSCA Yes
HS Code 29349990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TPP Usage And Synthesis
Chemical Propertiespurple glistening crystalline powder
Usesmeso-Tetraphenylporphine is a photosensitizer that is often used to create coordination complexes with metals such as cobalt and rhodium. Cobalt meso-tetraphenylporphrine is used as a hydrogen catalyst. Meso-tetraphenylporphrine compounds are used as inhibitors of microtubule assembly in human cervix carcinoma cells.
DefinitionChEBI: Tetraphenylporphyrin is a meso-substituted porphyrin and a phenylporphyrin.
Purification MethodsPurify TPP by chromatography on neutral (Grade I) alumina, and recrystallisation from CH2Cl2/MeOH or *C6H6. It forms complexes with metals. [Yamashita et al. J Phys Chem 91 3055 1987, Beilstein 26 III/IV 1958.]
TDCPP fire retardant meso-Tetraphenylporphine (1-3% chlorin) T101 fire retardant Flame retardant BP60 Red phosphorus flame retardant Flame retardant,intumescent,non-halogen Flame retardant for polyurethane TCEP fire retardant Flame retardant for PVC Water-soluble flame retardant,environmental-protection type TPP Inorganic millimicron fire-retardant 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE TCPP fire retardant Flame retardant CRP-1 Flame retardant AP Flame retardant,complex Liquid anti-flammability agent FR-113

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