ChemicalBook Product Catalog Chemical Reagents Organic reagents fatty acid (TRIMETHYLSILYL)ACETIC ACID

(TRIMETHYLSILYL)ACETIC ACID

(TRIMETHYLSILYL)ACETIC ACID Basic information
Product Name:(TRIMETHYLSILYL)ACETIC ACID
Synonyms:(trimethylsilyl)-aceticaci;TriMethylsilyl)acetic ac;(TRIMETHYLSILYL)ACETIC ACID;2-(TRIMETHYLSILYL)ACETIC ACID;(Trimethylsilyl)acetic acid, 98+%;2-trimethylsilylacetate;Acetic acid, 2-(trimethylsilyl)-;DK685
CAS:2345-38-2
MF:C5H12O2Si
MW:132.23
EINECS:219-067-4
Product Categories:Building Blocks;C1 to C5;Carbonyl Compounds;Carboxylic Acids;Chemical Synthesis;Organic Building Blocks;Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;C1 to C5;Carbonyl Compounds;Carboxylic Acids
Mol File:2345-38-2.mol
(TRIMETHYLSILYL)ACETIC ACID Structure
(TRIMETHYLSILYL)ACETIC ACID Chemical Properties
Melting point 39-42 °C(lit.)
Boiling point 90-95°C 10mm
density 0.8830 (estimate)
Fp 203 °F
storage temp. Sealed in dry,Room Temperature
solubility Sol ethereal solvents.
form solid
pka5.23±0.10(Predicted)
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Sensitive Moisture Sensitive
BRN 1679394
CAS DataBase Reference2345-38-2(CAS DataBase Reference)
NIST Chemistry ReferenceAcetic acid, (trimethylsilyl)-(2345-38-2)
EPA Substance Registry SystemAcetic acid, (trimethylsilyl)- (2345-38-2)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN3261
WGK Germany 2
RTECS AK0843500
F 3-10-21
TSCA No
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
(TRIMETHYLSILYL)ACETIC ACID Usage And Synthesis
Physical propertiesmp 40 °C.
UsesTrimethylsilylacetic Acid is a valuable reagent used in preparation of α,β-unsaturated carboxylic acids and α-trimethylsilylbutyrolactones,
Uses(Trimethylsilyl)acetic acid may be used in chemical synthesis.
PreparationObtained from the reaction of trimethylsilylmethylmagnesium chloride with carbon dioxide;3 can also be prepared by reaction of acetic acid with 2 equiv of lithium diisopropylamide, followed by chlorotrimethylsilane and hydrolysis.
(TRIMETHYLSILYL)ACETIC ACID Preparation Products And Raw materials
Raw materialsHydrochloric acid-->Diethyl ether-->Dichloromethane-->Sodium sulfate-->Sodium bicarbonate-->n-Butyllithium-->Aluminum chloride-->N-Bromosuccinimide-->Pentane-->Tetramethylsilane
(S)-4-((R)-2-BENZYLOXY-TRIDECYL)-3-HEXYL-3-TRIMETHYLSILANYL-OXETAN-2-ONE Fluoro(trimethylsilyl)acetic acid 2,4,6-trimethylphenyl ester (-)-BENZYLMETHYLPHENYLSILYLACETIC ACID Fluoro(trimethylsilyl)acetic acid 2,6-di-tert-butyl-4-methylphenyl ester METHYL (1-TRIMETHYLSILYL)ACRYLATE DIMETHYLPHENYLSILYLACETIC ACID METHYL TRIMETHYLSILYLDIFLUOROACETATE (Trimethylsilyl)acetic acid phenyl ester 2,2-DIFLUORO-2-(TRIMETHYLSILYL)ACETIC ACID ETHYL ESTER 2,2-DIFLUORO-2-(TRIMETHYLSILYL)ACETIC ACID PROPYL ESTER Fluoro(trimethylsilyl)acetic acid ethyl ester METHYL 2-(TRIMETHYLSILYL)PROPIONATE ETHYL 2-BROMO-2-(1,1,1-TRIMETHYLSILYL)ACETATE ETHYL (DIPHENYLMETHYLSILYL)ACETATE TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE 1-CARBOXYMETHYL-1,1,3,3,3-PENTAMETHYL-DISILMETHYLENE Bis(trimethylsilyl)acetic acid tert-butyl ester TRIMETHYLSILYL (TRIMETHYLSILYL)ACETATE
Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.