TERT-AMYL METHYL ETHER

TERT-AMYL METHYL ETHER Basic information
Product Name:TERT-AMYL METHYL ETHER
Synonyms:METHYL-TERT-AMYL ETHER;METHYL 2-METHYL-2-BUTYL ETHER;METHYL-(2-METHYLBUT-2-YL)ETHER;1,1-DIMETHYLPROPYL METHYL ETHER;tertiaryamylmethylether;tertiary-amylmethylether;tertiary-amylmethylether(tame);tert-pentylmethylether
CAS:994-05-8
MF:C6H14O
MW:102.17
EINECS:213-611-4
Product Categories:AM to AQGasoline, Diesel,&Petroleum;A;A-BChemical Class;Alcohols;AliphaticAlphabetic;Alpha Sort;ASTM D5441Analytical Standards;ASTM Petroleum and Petrochemical;ASTM Petroleum Standards;Method Specific;Volatiles/ Semivolatiles
Mol File:994-05-8.mol
TERT-AMYL METHYL ETHER Structure
TERT-AMYL METHYL ETHER Chemical Properties
Melting point -105.78°C (estimate)
Boiling point 85-86 °C (lit.)
density 0.76-0.78 g/mL at 25 °C (lit.)
vapor pressure 91hPa at 25℃
refractive index n20/D 1.389(lit.)
Fp 11 °F
storage temp. room temp
solubility Chloroform (Sparingly), Dichloromethane (Slightly), Methanol (Slightly)
form neat
Water Solubility 12.35g/L(20 ºC)
Merck 13,618
BRN 1731452
LogP1.55 at 20℃
CAS DataBase Reference994-05-8(CAS DataBase Reference)
EPA Substance Registry Systemtert-Amyl methyl ether (994-05-8)
Safety Information
Hazard Codes F,Xn,T
Risk Statements 11-22-38-41-39/23/24/25-23/24/25-67
Safety Statements 16-26-39-45-36/37-33-23-9-7
RIDADR UN 3271 3/PG 2
WGK Germany 3
RTECS EK4421000
3
HazardClass 3.1
PackingGroup II
HS Code 2909199090
Hazardous Substances Data994-05-8(Hazardous Substances Data)
ToxicityLD50 orl-rat: 2100 mg/kg JJATDK 15,313,1995
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
TERT-AMYL METHYL ETHER Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
UsesFuel additive for gasoline.
UsesTAME has been used as a reference standard for the determination of the analyte in Catalonian groundwater and soil samples by purge-and-trap gas chromatography/mass spectrometry (P&T-GC/MS) and in aqueous solutions by solid-phase microextraction (SPME) combined with GC-MS. It may be used as a reference standard for the identification of the analyte in gasoline-contaminated groundwater by GC combined with various detectors/quantification methods such as photoionization detector (PID), flame ionization detector (FID), or MS.
General Descriptiontert-Amyl methyl ether is an fuel ether oxygenate and has been quantitated in water by membrane extraction ion mobility spectrometry. tert-Amyl methyl ether is also referred to as 2-methoxy-2-methyl butane. Kinetics of ion exchange resin (Amberlyst 18) catalyzed tert-amyl methyl ether reactions have been investigated.
Flammability and ExplosibilityHighlyflammable
Safety ProfileModerately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.
TERT-AMYL METHYL ETHER Preparation Products And Raw materials
2,2,5,5-TETRAMETHYLTETRAHYDROFURAN Linalyl acetate BUTOPYRONOXYL MEDROXYPROGESTERONE (1R)-(+)-CAMPHANIC ACID ETHYL 2-ACETOXY-2-METHYLACETOACETATE CYTOCHALASIN E (+)-CAMPHANIC ACID CHLORIDE 2,2,5,5-TETRAMETHYLTETRAHYDROFURAN-3-ONE Fluocinolone acetonide CYTOCHALASIN A Trolox 2,2,5,5-TETRAMETHYL-3,4(2H,5H)-FURANDIONE HYDRAZONE OXIME DIHYDROCYTOCHALASIN B LABOTEST-BB LT00244777 TERT-AMYL METHYL ETHER 7-METHOXY-3,7-DIMETHYLOCTANAL 3,4-DIHYDRO-2,2-DIMETHYL-4-OXO-2H-PYRAN-6-CARBOXYLIC ACID

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