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N-(tert-Butoxycarbonyl)-L-glutamine

N-(tert-Butoxycarbonyl)-L-glutamine Basic information
Product Name:N-(tert-Butoxycarbonyl)-L-glutamine
Synonyms:n2-[(1,1-dimethylethoxy)carbonyl]-l-glutamin;BOC-GLN;BOC-GLUTAMINE;(S)-5-AMINO-2-(TERT-BUTOXYCARBONYLAMINO)-5-OXOPENTANOIC ACID;N(ɑ)-Boc-L-glutamine, 98+%;BOC-L-GLUTAMINE extrapure;Boc-L-glutamine, Nα-(tert-Butoxycarbonyl)-L-glutamine;L-Glutamine, N(2)-[(1,1-dimethylethoxy)carbonyl]-
CAS:13726-85-7
MF:C10H18N2O5
MW:246.26
EINECS:237-296-8
Product Categories:Amino Acids & Derivatives;Chiral Reagents;Amino Acid Derivatives;Amino Acids;Glutamine [Gln, Q];Boc-Amino Acids and Derivative;Amino Acids (N-Protected);Biochemistry;Boc-Amino Acids;Boc-Amino acid series
Mol File:13726-85-7.mol
N-(tert-Butoxycarbonyl)-L-glutamine Structure
N-(tert-Butoxycarbonyl)-L-glutamine Chemical Properties
Melting point 113-116 °C (dec.)(lit.)
alpha -3.5 º (c=2,C2H5OH)
Boiling point 389.26°C (rough estimate)
density 1.2430 (rough estimate)
refractive index -4 ° (C=2, EtOH)
storage temp. Sealed in dry,2-8°C
solubility Soluble in DMSO and methanol. Soluble in 1 mmole in 2 ml DMF.
form Solid
pka3.84±0.10(Predicted)
color White
optical activity[α]20/D 3.5°, c = 1 in ethanol
BRN 2127805
CAS DataBase Reference13726-85-7(CAS DataBase Reference)
EPA Substance Registry SystemL-Glutamine, N2-[(1,1-dimethylethoxy)carbonyl]- (13726-85-7)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
TSCA Yes
HS Code 29241990
MSDS Information
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N-(tert-Butoxycarbonyl)-L-glutamine English
SigmaAldrich English
ACROS English
ALFA English
N-(tert-Butoxycarbonyl)-L-glutamine Usage And Synthesis
Chemical PropertiesWhite fine crystalline powder
UsesProtected Glutamine.
UsesIt is employed in the synthesis and analgesic activity of human .beta.-endorphin.
N-(tert-Butoxycarbonyl)-L-glutamine Preparation Products And Raw materials
Preparation Products3-AMINO-PIPERIDINE-2,6-DIONE-->N-Boc-N'-(9-xanthenyl)-L-glutamine-->Butanoic acid, 4-cyano-2-[[(1,1-dimethylethoxy)carbonyl]amino]-, (2S)--->(S)-Tert-Butyl (1,5-diaMino-1,5-dioxopentan-2-yl)carbaMate
BOC-L-Serine BOC-CYS-OH Boc-D-Valine Boc-L-Glutamic acid BOC-L-Asparagine BOC-L-GLN-O-CH2-PHI-CH2-COOH NALPHA-tert-Butoxycarbonyl-D-glutamine 4-nitrophenyl ester N-tert-Butoxycarbonyl-L-glutamine-N-hydroxysuccinimide est NALPHA-tert-Butoxycarbonyl-L-glutamine 4-nitrophenyl ester BOC-GLU(EDANS)-OH L-Glutamine BOC-N-GAMMA-ETHYL-L-GLUTAMINE N-ALPHA-T-BOC-L-GLUTAMINE DICYCLOHEXYLAMMONIUM SALT N-(tert-Butoxycarbonyl)-L-glutamine BOC-GAMMA-GLU-LYS-OH L-Glutamine-15N2, N-t-Boc derivative, N-(tert-Butoxycarbonyl)-L-glutamine-15N2 N-Boc-N'-(9-xanthenyl)-L-glutamine NALPHA-(TERT-BUTOXYCARBONYL)-D-GLUTAMINE,N-tert-Butoxycarbonyl-D-glutamine ,n(à)-tert-butoxycarbonyl-d-glutamine
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