N,N,N',N'-Tetramethyl-1,6-hexanediamine

N,N,N',N'-Tetramethyl-1,6-hexanediamine Basic information
Product Name:N,N,N',N'-Tetramethyl-1,6-hexanediamine
Synonyms:u1000(amine);LUPRAGEN(R) N 500;N,N,N',N'-TETRAMETHYL-1,3-DIAMINOHEXANE;N,N,N′,N′-Tetramethylhexamethylendiamin;Tetramethylhexamethylene diamine;1,6-BIS(DIMETHYLAMINO)HEXANE;3,3,4,4-TETRAMETHYLHEXANE;N,N,N',N'-TETRAMETHYL HEXAMETHYLENE DIAMINE
CAS:111-18-2
MF:C10H24N2
MW:172.31
EINECS:203-842-9
Product Categories:Amine Monomers;Monomers;Tertiary Amines;Miscellaneous
Mol File:111-18-2.mol
N,N,N',N'-Tetramethyl-1,6-hexanediamine Structure
N,N,N',N'-Tetramethyl-1,6-hexanediamine Chemical Properties
Melting point -46 °C
Boiling point 209-210 °C(lit.)
density 0.806 g/mL at 25 °C(lit.)
vapor pressure 12.4Pa at 20℃
refractive index n20/D 1.4359(lit.)
Fp 165 °F
storage temp. Sealed in dry,Room Temperature
solubility miscible
form Liquid
pka10.07±0.28(Predicted)
color Clear colorless to yellow
Water Solubility miscible
LogP1.99 at 23℃
CAS DataBase Reference111-18-2(CAS DataBase Reference)
NIST Chemistry Reference(CH3)2N(CH2)6N(CH3)2(111-18-2)
EPA Substance Registry SystemN,N,N',N'-Tetramethyl-1,6-hexanediamine (111-18-2)
Safety Information
Hazard Codes T
Risk Statements 22-24-34-23/24
Safety Statements 26-36/37/39-45
RIDADR UN 3390 6.1/PG 1
WGK Germany 1
RTECS MO1370000
HazardClass 8
PackingGroup III
HS Code 29212900
MSDS Information
ProviderLanguage
N,N,N',N'-Tetramethyl-1,6-hexanediamine English
SigmaAldrich English
ACROS English
N,N,N',N'-Tetramethyl-1,6-hexanediamine Usage And Synthesis
Chemical Propertiesclear colorless to yellow liquid
UsesN,N,N'',N''-Tetramethyl-1,6-hexanediamine is used in the synthesis of fluorene containing poly(arylene ether sulfone) as anion exchange membranes for alkaline fuel cells.
PreparationN,N,N',N'-Tetramethyl-1,6-hexanediamine can be made from adipodinitrile and dimethylamine or from 1,6- hexanediamine and formaldehyde.
Flammability and ExplosibilityNotclassified
N,N,N',N'-Tetramethyl-1,6-hexanediamine Preparation Products And Raw materials
Raw materialsN,N,N',N'-tetraMethylhexanediaMide-->1-DIMETHYLAMINO-2-PROPYNE-->1,6-DIIODOHEXANE-->6-(DIMETHYLAMINO)HEXYLAMINE-->Adiponitrile-->Hexamethylenediamine
Preparation ProductsHEXANE-1,6-DIYLBIS(METHYLCARBAMIC CHLORIDE)
N,N'-(2,3-dihydroxybenzyl)-N,N,N',N'-tetramethyl-1,6-hexanediamine CDTA CALYCANTHINE 1,6-DIAMINOHEXANE-N,N,N',N'-TETRAACETIC ACID HEXAMETHONIUM CHLORIDE (-)-(1S,2R)-CIS-3,4-DICHLORO-N-METHYL-N-[2-(1-PYRROLIDINYL)-CYCLOHEXYL]-BENZENEACETAMIDE TARTRATE Chaetocin N,N,N',N'-TETRAMETHYL-1,6-HEXANEDIAMINE, [1,6-BIS(DIMETHYLAMINO)HEXANE] HDTMPA trans-(-3,4-Dichloro-N-methyl-N-[2-(1-pyrrolidinyl)cyclohexyl]benzeneacetamidehydrochloride TRANS-1,2-DIAMINOCYCLOHEXANE-N,N,N',N'-TETRAACETIC ACID MONOHYDRATE 1,2-Cyclohexylenedinitrilotetraacetic acid HEXAMETHONIUM IODIDE (+/-)-(5ALPHA,7ALPHA,8BETA)-3,4-DICHLORO-N-METHYL-N-(7-[1-PYRROLIDINYL]-1-OXASPIRO[4.5]DEC-8-YL)BENZENEACETAMIDE MESYLATE HEXANE-1,6-BIS(TRIBUTYLAMMONIUM BROMIDE) N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)hexanediamine propane,1,3-dibromo-,polymerwithn,n,n’,n’-tetramethyl-1,6-hexanediamin CDTA DISODIUM SALT

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